A Gamma Radiolysis Study of UO{sub 2}F{sub 2} 0.4H{sub 2}O Using Spent Nuclear Fuel Elements from the High Flux Isotope Reactor

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The development of a standard for the safe, long-term storage of {sup 233}U-containing materials resulted in the identification of several needed experimental studies. These studies were largely related to the potential for the generation of unacceptable pressures or the formation of deleterious products during storage of uranium oxides. The primary concern was that these conditions could occur as a result of the radiolysis of residual impurities--specifically fluorides and water-by the high radiation fields associated with {sup 233}U/{sup 232}U-containing materials. This report documents the results from a gamma radiolysis experiment in which UO{sub 2}F{sub 2} {center_dot} 0.4H{sub 2}O was loaded in ... continued below

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36 pages

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Icenhour, A.S. January 24, 2002.

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Description

The development of a standard for the safe, long-term storage of {sup 233}U-containing materials resulted in the identification of several needed experimental studies. These studies were largely related to the potential for the generation of unacceptable pressures or the formation of deleterious products during storage of uranium oxides. The primary concern was that these conditions could occur as a result of the radiolysis of residual impurities--specifically fluorides and water-by the high radiation fields associated with {sup 233}U/{sup 232}U-containing materials. This report documents the results from a gamma radiolysis experiment in which UO{sub 2}F{sub 2} {center_dot} 0.4H{sub 2}O was loaded in helium. This experiment was performed using spent nuclear fuel elements from the High Flux Isotope Reactor as the gamma source and was a follow-on to experiments conducted previously. It was found that upon gamma irradiation, the UO{sub 2}F{sub 2} {center_dot} 0.4H{sub 2}O released 0{sub 2} with an initial G(O{sub 2}) = 0.01 molecule O{sub 2}/100 eV and that some of the uranium was reduced from U(VI) to U(IV). The high total dose achieved in the SNF elements was sufficient to reach a damage limit for the UO{sub 2}F{sub 2} {center_dot} 0.4H{sub 2}O. This damage limit, measured in terms of the amount of the U(IV) produced, was found to be about 9 wt%.

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36 pages

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  • Other Information: PBD: 24 Jan 2002

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  • Report No.: ORNL/TM-2001/138
  • Grant Number: AC05-00OR22725
  • DOI: 10.2172/814115 | External Link
  • Office of Scientific & Technical Information Report Number: 814115
  • Archival Resource Key: ark:/67531/metadc735276

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Office of Scientific & Technical Information Technical Reports

Reports, articles and other documents harvested from the Office of Scientific and Technical Information.

Office of Scientific and Technical Information (OSTI) is the Department of Energy (DOE) office that collects, preserves, and disseminates DOE-sponsored research and development (R&D) results that are the outcomes of R&D projects or other funded activities at DOE labs and facilities nationwide and grantees at universities and other institutions.

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  • January 24, 2002

Added to The UNT Digital Library

  • Oct. 18, 2015, 6:40 p.m.

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  • March 31, 2016, 12:51 p.m.

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Icenhour, A.S. A Gamma Radiolysis Study of UO{sub 2}F{sub 2} 0.4H{sub 2}O Using Spent Nuclear Fuel Elements from the High Flux Isotope Reactor, report, January 24, 2002; United States. (digital.library.unt.edu/ark:/67531/metadc735276/: accessed April 20, 2018), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.