Discharge-Flow/Chemiluminescence and Flash-Photolysis/Resonance Fluorescence Studies of the Reaction O + SiH4 at Room Temperature

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Article on discharge-flow/chemiluminescence and flash-photolysis/resonance fluorescence studies of the reaction O + SiH4 at room temperature.

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19 p.

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Taylor, Craig A.; Ding, Luying & Marshall, Paul March 1, 1993.

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Article on discharge-flow/chemiluminescence and flash-photolysis/resonance fluorescence studies of the reaction O + SiH4 at room temperature.

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19 p.

Notes

Abstract: DF-CL studies using NO2 chemiluminescence detection of O yielded a rate constant k1 for O + SiH4 of (2.6 ± 0.5)×10−13 cm3 s−1 at 295 K, where the 95% confidence interval reflects accuracy. FP-RF studies using flash photolysis of SO2 followed by time-resolved vuv fluorescence detection of O at 295 K yielded k1 = (3.0 ± 0.5) ×10−13 cm3 s−1. These results are in good accord with most previous measurements and lead to a combined best estimate of k1 = (3.2 ± 0.4) × 10−13 cm3 s−1. The DF-CL and FP-RF methods appear to have little unrecognized systematic error.

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  • International Journal of Chemical Kinetics, 1993, Hoboken: John Wiley & Sons, pp. 183-191

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  • Publication Title: International Journal of Chemical Kinetics
  • Volume: 25
  • Issue: 3
  • Page Start: 183
  • Page End: 191
  • Peer Reviewed: Yes

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  • March 1, 1993

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  • Oct. 2, 2015, 9:40 a.m.

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  • Oct. 8, 2015, 1:02 p.m.

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Taylor, Craig A.; Ding, Luying & Marshall, Paul. Discharge-Flow/Chemiluminescence and Flash-Photolysis/Resonance Fluorescence Studies of the Reaction O + SiH4 at Room Temperature, article, March 1, 1993; [Hoboken, New Jersey]. (digital.library.unt.edu/ark:/67531/metadc725859/: accessed October 21, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT College of Arts and Sciences.