Thermochemical Investigations of Associated Solutions: 4. Calculation of Carbazole-Dibutyl Ether Association Constants from Measured Solubility in Binary Solvent Mixtures

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Article on thermochemical investigations of associated solutions and calculation of carbazole-dibutyl ether association constants from measured solubility in binary solvent mixtures.

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3 p.

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McCargar, James W. July 1, 1987.

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Article on thermochemical investigations of associated solutions and calculation of carbazole-dibutyl ether association constants from measured solubility in binary solvent mixtures.

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3 p.

Notes

Abstract: Experimental solubilities are reported for anthracene and carbazole in binary dibutyl ether plus n-hexadecane and dibutyl ether plus squalane solvent mixtures at 25 degrees C. Results of these measurements, used in conjunction with the extended nearly ideal binary solvent (NIBS) model, enabled calculation of the carbazole-dibutyl ether association constant. The numerical value obtained was independent of the hydrocarbon cosolvent, and compared favorably with previously reported values based on carbazole solubilities in solvent mixtures containing much smaller alkane cosolvents.

© 1987 by the American Pharmaceutical Association.

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  • Journal of Pharmaceutical Sciences, 1987, Washington D.C.: American Pharmaceutical Association, pp. 572-574

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  • Publication Title: Journal of Pharmaceutical Sciences
  • Volume: 76
  • Issue: 7
  • Page Start: 572
  • Page End: 574
  • Pages: 3
  • Peer Reviewed: Yes

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  • July 1, 1987

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  • February 9, 1987

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  • April 21, 1987

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  • Oct. 2, 2015, 9:40 a.m.

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McCargar, James W. Thermochemical Investigations of Associated Solutions: 4. Calculation of Carbazole-Dibutyl Ether Association Constants from Measured Solubility in Binary Solvent Mixtures, article, July 1, 1987; [Washington, D.C.]. (digital.library.unt.edu/ark:/67531/metadc725843/: accessed December 14, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT College of Arts and Sciences.