The Solvation Properties of the Aliphatic Alcohols

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Article on the solvation properties of the aliphatic alcohols.

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13 p.

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Abraham, M. H. (Michael H.); Le, Joelle & Acree, William E. (William Eugene) 1999.

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Description

Article on the solvation properties of the aliphatic alcohols.

Physical Description

13 p.

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Abstract: Solubilities of solute gases and vapours, as log L, where L is the Ostwald solubility coefficient, in the alkan-1-ols from methanol to decan-1-ol have been correlated through the solvation equation of Abraham. It is shown that there is a regular progression of solvent properties from methanol to decan-1-ol, except for the solvent hydrogen-bond basicity that remains the same along the series, and, indeed, is the same as that of water. A slightly different solvation equation is used to correlate the partition of solutes from water to the dry alkanols. For the longer chain alkanols, the coefficients in the solvation equations approach those in equations for partition from water to the wet (water-saturated) alkanols, showing that the solvation properties of the wet and dry alkanols are quite close for the higher alkanol homologues.

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  • Collection of Czechoslovak Chemical Communications, 1999, Prague: Institute of Organic Chemistry and Biochemistry (Akademie věd České republiky), pp. 1748-1759

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Publication Information

  • Publication Title: Collection of Czechoslovak Chemical Communications
  • Volume: 64
  • Page Start: 1748
  • Page End: 1760
  • Pages: 13
  • Peer Reviewed: Yes

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  • 1999

Submitted Date

  • July 1, 1999

Accepted Date

  • October 7, 1999

Added to The UNT Digital Library

  • Oct. 2, 2015, 9:40 a.m.

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Abraham, M. H. (Michael H.); Le, Joelle & Acree, William E. (William Eugene). The Solvation Properties of the Aliphatic Alcohols, article, 1999; [Prague, Czech Republic]. (digital.library.unt.edu/ark:/67531/metadc725819/: accessed September 24, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT College of Arts and Sciences.