Convalency of Neptunium(IV) Organometallics from {sup 237}Np Moessbauer Spectra

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The results of {sup 237}Np Moessbauer spectra provide a picture of the bonding of {sup 237}Np organometallics and their uranium analogues that could be obtained by no other method. In essence, Moessbauer results give a view of the compound from the position of the neptunium nucleus; the work summarized in this paper shows that the {sup 237}Np isomer shift results are consistent with available data and provide a useful picture of the bonding in actinide organometallics.

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Karraker, D.G. March 15, 2001.

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The results of {sup 237}Np Moessbauer spectra provide a picture of the bonding of {sup 237}Np organometallics and their uranium analogues that could be obtained by no other method. In essence, Moessbauer results give a view of the compound from the position of the neptunium nucleus; the work summarized in this paper shows that the {sup 237}Np isomer shift results are consistent with available data and provide a useful picture of the bonding in actinide organometallics.

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  • 179th National American Chemical Society Meeting, Houston, TX (US), 03/24/1980--03/28/1980

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  • Report No.: DP-MS-79-93 Rev. 1
  • Grant Number: AC09-76SR00001
  • Office of Scientific & Technical Information Report Number: 780257
  • Archival Resource Key: ark:/67531/metadc723585

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  • March 15, 2001

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  • Sept. 29, 2015, 5:31 a.m.

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  • May 4, 2016, 11:35 p.m.

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Karraker, D.G. Convalency of Neptunium(IV) Organometallics from {sup 237}Np Moessbauer Spectra, article, March 15, 2001; South Carolina. (digital.library.unt.edu/ark:/67531/metadc723585/: accessed September 24, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.