Provide thermogravimetric analysis data to performance assessment

PDF Version Also Available for Download.

Description

Recent experimental testing has investigated the effect of a deposited mixed salt on the corrosion of carbon steel in high relative humidity air. This result is compared with previous studies where pure sodium chloride was deposited. There are aspects of the degradation process which are significantly different when the different salts are deposited. With deposited sodium chloride, corrosion occurs almost immediately after introduction of 80% RH air. With deposited mixed salts, there is an initial inhibition of corrosion in 80% RH air. After the initial inhibition period, corrosion occurs at localized regions of the specimen. At longer times, the specimen ... continued below

Physical Description

10 p.

Creation Information

Gdowski, G. January 1, 1998.

Context

This report is part of the collection entitled: Office of Scientific & Technical Information Technical Reports and was provided by UNT Libraries Government Documents Department to Digital Library, a digital repository hosted by the UNT Libraries. More information about this report can be viewed below.

Who

People and organizations associated with either the creation of this report or its content.

Author

Sponsor

Publisher

Provided By

UNT Libraries Government Documents Department

Serving as both a federal and a state depository library, the UNT Libraries Government Documents Department maintains millions of items in a variety of formats. The department is a member of the FDLP Content Partnerships Program and an Affiliated Archive of the National Archives.

Contact Us

What

Descriptive information to help identify this report. Follow the links below to find similar items on the Digital Library.

Description

Recent experimental testing has investigated the effect of a deposited mixed salt on the corrosion of carbon steel in high relative humidity air. This result is compared with previous studies where pure sodium chloride was deposited. There are aspects of the degradation process which are significantly different when the different salts are deposited. With deposited sodium chloride, corrosion occurs almost immediately after introduction of 80% RH air. With deposited mixed salts, there is an initial inhibition of corrosion in 80% RH air. After the initial inhibition period, corrosion occurs at localized regions of the specimen. At longer times, the specimen suffers extensive corrosion. A very porous and non-adherent corrosion product forms and readily spalls. The initial inhibition of the corrosion with the deposited mixed salt is most likely due to the bicarbonate component. Bicarbonate is a known inhibitor of general corrosion of carbon steel [Thomas, 1994] and a promoter of localized corrosion at moderate alkalinity when chloride ions are present [Marsh, 1985]. The results of this testing indicate that the bicarbonate component of thin water layers can initially inhibit corrosion of the carbon steel. With time, however, inhibition is lost. A mechanism for this loss of inhibition is suggested. It is plausible that moderately alkaline bicarbonate aqueous solutions could develop on the surface of a waste package due to Yucca Mountain water contacting the waste packages. Aqueous conditions might develop where carbon steel is susceptible to localized corrosion [Dunn, 1998]. The initial test results presented here suggest that the inhibition of general corrosion, and hence, the promotion of localized corrosion of carbon steel by thin aqueous bicarbonate-chloride layers may not be sustainable. Additional testing is underway to further understand the effects of thin aqueous solution chemistry on carbon steel corrosion.

Physical Description

10 p.

Notes

OSTI as DE98057736

Other: FDE: PDF; PL:

Source

  • Other Information: PBD: 1 Jan 1998

Language

Item Type

Identifier

Unique identifying numbers for this report in the Digital Library or other systems.

  • Other: DE98057736
  • Report No.: UCRL-ID--129842
  • Grant Number: W-7405-ENG-48
  • DOI: 10.2172/676812 | External Link
  • Office of Scientific & Technical Information Report Number: 676812
  • Archival Resource Key: ark:/67531/metadc712213

Collections

This report is part of the following collection of related materials.

Office of Scientific & Technical Information Technical Reports

Reports, articles and other documents harvested from the Office of Scientific and Technical Information.

Office of Scientific and Technical Information (OSTI) is the Department of Energy (DOE) office that collects, preserves, and disseminates DOE-sponsored research and development (R&D) results that are the outcomes of R&D projects or other funded activities at DOE labs and facilities nationwide and grantees at universities and other institutions.

What responsibilities do I have when using this report?

When

Dates and time periods associated with this report.

Creation Date

  • January 1, 1998

Added to The UNT Digital Library

  • Sept. 12, 2015, 6:31 a.m.

Description Last Updated

  • April 6, 2017, 6:27 p.m.

Usage Statistics

When was this report last used?

Yesterday: 0
Past 30 days: 0
Total Uses: 3

Interact With This Report

Here are some suggestions for what to do next.

Start Reading

PDF Version Also Available for Download.

International Image Interoperability Framework

IIF Logo

We support the IIIF Presentation API

Gdowski, G. Provide thermogravimetric analysis data to performance assessment, report, January 1, 1998; California. (digital.library.unt.edu/ark:/67531/metadc712213/: accessed September 21, 2018), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.