Adsorption of polystyrene sulfonate to the air surface of water by neutron reflectivity

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The adsorption of the strong polyelectrolyte polystyrene sulfonate (PSS) to the air surface of dilute aqueous solutions was investigated as a function of molecular weight and salt concentration. Detailed segment profiles of the deuterated polymer were determined by neutron reflection. Surface activity was also examined through surface tension measurements. In general, the segment profiles are composed of a thin layer (10--20 {angstrom} thick) of high concentration at the air surface, followed by a distinct second layer of much lower segment concentration that extends to larger depths into the liquid. The high segment density at the air surface is due to ... continued below

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31 p.

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YIM,HYUN; KENT,MICHAEL S.; MATHESON,AARON J.; IVKOV,R.; SATIJA,S.; MAJEWSKI,J. et al. May 16, 2000.

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  • Sandia National Laboratories
    Publisher Info: Sandia National Labs., Albuquerque, NM, and Livermore, CA
    Place of Publication: Albuquerque, New Mexico

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The adsorption of the strong polyelectrolyte polystyrene sulfonate (PSS) to the air surface of dilute aqueous solutions was investigated as a function of molecular weight and salt concentration. Detailed segment profiles of the deuterated polymer were determined by neutron reflection. Surface activity was also examined through surface tension measurements. In general, the segment profiles are composed of a thin layer (10--20 {angstrom} thick) of high concentration at the air surface, followed by a distinct second layer of much lower segment concentration that extends to larger depths into the liquid. The high segment density at the air surface is due to a strong surface attraction, arising from the low surface tension of the PSS backbone relative to the surface tension of water. At low salt concentration, the profiles tend toward a single dense layer, suggesting that the chains lie nearly flat at the interface in that limit. The adsorbed amount increases with salt concentration, with a stronger dependence for higher molecular weight chains. The adsorbed amounts at the air/water interface are higher than reported previously for PSS adsorbed onto neutral solid surfaces, consistent with the fact that the air-liquid interface provides a stronger surface attraction. While the trends of adsorbed amount and layer thickness with salt concentration and molecular weight are in good agreement with numerical self-consistent field lattice calculations, the measured bilayer profiles are rather different from the smoothly decaying theoretical profiles. The surface tensions of the PSS solutions are significantly lowered relative to those of pure salt solutions. Combining the reflectivity and surface tension measurements, an approximately linear relationship is established between the surface pressure and the PSS adsorbed amount.

Physical Description

31 p.

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OSTI as DE00755611

Medium: P; Size: 31 pages

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  • Journal Name: Macromolecules; Other Information: Submitted to Macromolecules

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  • Report No.: SAND2000-1229J
  • Grant Number: AC04-94AL85000
  • Office of Scientific & Technical Information Report Number: 755611
  • Archival Resource Key: ark:/67531/metadc710774

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Creation Date

  • May 16, 2000

Added to The UNT Digital Library

  • Sept. 12, 2015, 6:31 a.m.

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  • April 12, 2017, 1:10 p.m.

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YIM,HYUN; KENT,MICHAEL S.; MATHESON,AARON J.; IVKOV,R.; SATIJA,S.; MAJEWSKI,J. et al. Adsorption of polystyrene sulfonate to the air surface of water by neutron reflectivity, article, May 16, 2000; Albuquerque, New Mexico. (digital.library.unt.edu/ark:/67531/metadc710774/: accessed September 25, 2018), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.