A MATHEMATICAL MODEL FOR MAGNESIUM CHLORIDE-FATTY ACID ADDUCTS IN ELECTROSPRAY IONIZATION MASS SPECTROMETRY

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The formation of adducts among analyte species is a well known phenomenon in electrospray ionization mass spectrometry (ESI-MS). The presence of salts usually promotes the formation of adducts by electrostatic and van de waalse bonds among various ions present in solution. In this study, the authors describe a simple mathematical model to explain the patterns for mass distribution and peak intensity for adducts formed by magnesium chloride and various fatty acid anions.

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3 pages

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OUYANG,S. & VAIRAVAMURTHY,M.A. June 13, 1999.

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Description

The formation of adducts among analyte species is a well known phenomenon in electrospray ionization mass spectrometry (ESI-MS). The presence of salts usually promotes the formation of adducts by electrostatic and van de waalse bonds among various ions present in solution. In this study, the authors describe a simple mathematical model to explain the patterns for mass distribution and peak intensity for adducts formed by magnesium chloride and various fatty acid anions.

Physical Description

3 pages

Notes

OSTI as DE00759032

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  • 47TH ASMS CONFERENCE ON MASS SPECTROMETRY AND ALLIED TOPICS, DALLAS, TX (US), 06/13/1999--06/17/1999

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  • Report No.: BNL--67052
  • Report No.: KC040302
  • Grant Number: AC02-98CH10886
  • Office of Scientific & Technical Information Report Number: 759032
  • Archival Resource Key: ark:/67531/metadc710263

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  • June 13, 1999

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  • Sept. 12, 2015, 6:31 a.m.

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  • Nov. 9, 2015, 1 p.m.

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OUYANG,S. & VAIRAVAMURTHY,M.A. A MATHEMATICAL MODEL FOR MAGNESIUM CHLORIDE-FATTY ACID ADDUCTS IN ELECTROSPRAY IONIZATION MASS SPECTROMETRY, article, June 13, 1999; Upton, New York. (digital.library.unt.edu/ark:/67531/metadc710263/: accessed October 21, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.