Tetrahedral-Network Organo-Zincophosphates: Syntheses and Structures of (N(2)C(6)H(14)).Zn(HPO(4))(2).H(2)O, H(3)N(CH(2))(3)NH(3).Zn(2)(HPO(4))(3) and (N(2)C(6)H(14)).Zn(3)(HPO(4))(4)

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The solution-mediated syntheses and single crystal structures of (N<sub>2</sub>C<sub>6</sub>H<sub>14</sub>)&middot;Zn(HPO<sub>4</sub>)<sub>2</sub>&middot;H<sub>2</sub>O (I), H<sub>3</sub>N(CH<sub>2</sub>)<sub>3</sub>NH<sub>3</sub>&middot;Zn<sub>2</sub>(HPO<sub>4</sub>)<sub>3</sub> (II), and (N<sub>2</sub>C<sub>6</sub>H<sub>14</sub>)&middot;Zn<sub>3</sub>(HPO<sub>4</sub>)<sub>4</sub> (III) are described. These phases contain vertex-sharing Zn0<sub>4</sub> and HP0<sub>4</sub> tetrahedra, accompanied by doubly- protonated organic cations. Despite their formal chemical relationship, as members of the series of t&middot;Zn<sub>n</sub>(HP0<sub>4</sub>)<sub>n+1</sub> (t= template, n = 1-3), these phases adopt fimdamentally different crystal structures, as one-dimensional, two-dimensional, and three-dimensional Zn0<sub>4</sub>/HP0<sub>4</sub> networks, for I, II, and III respectively. Similarities and differences to some other zinc phosphates are briefly discussed. Crystal data: (N<sub>2</sub>C<sub>6</sub>H<sub>14</sub>)&middot;Zn(HP0<sub>4</sub>)<sub>2</sub>&middot;H<sub>2</sub>0, M<sub>r</sub> = 389.54, monoclinic, space group P2<sub>1</sub>/n (No. 14), a = 9.864 (4) &Aring;, b = 8.679 (4) ... continued below

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Chavez, Alejandra V.; Hannooman, Lakshitha; Harrison, William T.A. & Nenoff, Tina M. May 7, 1999.

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    Publisher Info: Sandia National Laboratories (SNL), Albuquerque, NM, and Livermore, CA
    Place of Publication: Albuquerque, New Mexico

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The solution-mediated syntheses and single crystal structures of (N<sub>2</sub>C<sub>6</sub>H<sub>14</sub>)&middot;Zn(HPO<sub>4</sub>)<sub>2</sub>&middot;H<sub>2</sub>O (I), H<sub>3</sub>N(CH<sub>2</sub>)<sub>3</sub>NH<sub>3</sub>&middot;Zn<sub>2</sub>(HPO<sub>4</sub>)<sub>3</sub> (II), and (N<sub>2</sub>C<sub>6</sub>H<sub>14</sub>)&middot;Zn<sub>3</sub>(HPO<sub>4</sub>)<sub>4</sub> (III) are described. These phases contain vertex-sharing Zn0<sub>4</sub> and HP0<sub>4</sub> tetrahedra, accompanied by doubly- protonated organic cations. Despite their formal chemical relationship, as members of the series of t&middot;Zn<sub>n</sub>(HP0<sub>4</sub>)<sub>n+1</sub> (t= template, n = 1-3), these phases adopt fimdamentally different crystal structures, as one-dimensional, two-dimensional, and three-dimensional Zn0<sub>4</sub>/HP0<sub>4</sub> networks, for I, II, and III respectively. Similarities and differences to some other zinc phosphates are briefly discussed. Crystal data: (N<sub>2</sub>C<sub>6</sub>H<sub>14</sub>)&middot;Zn(HP0<sub>4</sub>)<sub>2</sub>&middot;H<sub>2</sub>0, M<sub>r</sub> = 389.54, monoclinic, space group P2<sub>1</sub>/n (No. 14), a = 9.864 (4) &Aring;, b = 8.679 (4) &Aring;, c = 15.780 (3) &Aring;, &beta; = 106.86 (2)&deg;, V= 1294.2 (8) &Aring;<sup>3</sup>, Z = 4, R(F) = 4.58%, R<sub>W</sub>(F) = 5.28% [1055 reflections with I >3&sigma;(I)]. H<sub>3</sub>N(CH<sub>2</sub>)<sub>3</sub>NH<sub>3</sub>&middot;Zn<sub>2</sub>(HP0<sub>4</sub>)<sub>3</sub>, M<sub>r</sub> = 494.84, monoclinic, space group P2<sub>1</sub>/c (No. 14), a= 8.593 (2)&Aring;, b= 9.602 (2)&Aring;, c= 17.001 (3)&Aring;, &beta;= 93.571 (8)&deg;, V = 1400.0 (5) &Aring;<sup>3</sup>, Z = 4, R(F) = 4.09%, R<sub>W</sub>(F) = 4.81% [2794 reflections with I > 3&sigma; (I)]. (N<sub>2</sub>C<sub>6</sub>H<sub>14</sub>)&middot;Zn<sub>3</sub>(HP0<sub>4</sub>)<sub>4</sub>, M<sub>r</sub>= 694.25, monoclinic, space group P2<sub>1</sub>/n (No. 14), a = 9.535 (2) &Aring;, b = 23.246 (4)&Aring;, c= 9.587 (2)&Aring;, &beta;= 117.74 (2)&deg;, V= 1880.8 (8) &Aring;<sup>3</sup>, Z = 4, R(F) = 3.23%, R<sub>W</sub>(F) = 3.89% [4255 reflections with 1> 3&sigma;(I)].

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  • Other: DE00007050
  • Report No.: SAND99-1232J
  • Grant Number: AC04-94AL85000
  • Office of Scientific & Technical Information Report Number: 7050
  • Archival Resource Key: ark:/67531/metadc709681

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Thumbnail image of item number 1 in: 'Tetrahedral-Network Organo-Zincophosphates: Syntheses and Structures of (N(2)C(6)H(14)).Zn(HPO(4))(2).H(2)O, H(3)N(CH(2))(3)NH(3).Zn(2)(HPO(4))(3) and (N(2)C(6)H(14)).Zn(3)(HPO(4))(4)'.
Thumbnail image of item number 2 in: 'Tetrahedral-Network Organo-Zincophosphates: Syntheses and Structures of (N(2)C(6)H(14)).Zn(HPO(4))(2).H(2)O, H(3)N(CH(2))(3)NH(3).Zn(2)(HPO(4))(3) and (N(2)C(6)H(14)).Zn(3)(HPO(4))(4)'.
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Chavez, Alejandra V.; Hannooman, Lakshitha; Harrison, William T.A. & Nenoff, Tina M. Tetrahedral-Network Organo-Zincophosphates: Syntheses and Structures of (N(2)C(6)H(14)).Zn(HPO(4))(2).H(2)O, H(3)N(CH(2))(3)NH(3).Zn(2)(HPO(4))(3) and (N(2)C(6)H(14)).Zn(3)(HPO(4))(4), article, May 7, 1999; Albuquerque, New Mexico. (digital.library.unt.edu/ark:/67531/metadc709681/: accessed January 18, 2019), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.