Syntheses and Structures of the Open-Framework Phases (CH(3)NH(3))(3).Zn(4)O(AsO(4))(3) and (CH(3)NH(3))(3).Zn(4)O(PO(4))(3) Related to the M(3)Zn(4)O(XO(4)(3).nH(2)O Family

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The solution-mediated syntheses and single crystal structures of (CH<sub>3</sub>NH<sub>3</sub>)<sub>3</sub>&middot;Zn<sub>4</sub>0(AsO<sub>4</sub>)<sub>3</sub> and (CH<sub>3</sub>NH<sub>3</sub>)<sub>3</sub>&middot;Zn<sub>4</sub>O(P0<sub>4</sub>)<sub>3</sub> are reported. These compounds are built up from vertex-sharing three-dimensional Zn0<sub>4</sub> + AsO<sub>4</sub>/P0<sub>4</sub> tetrahedral frameworks encapsulating methylammonium cations in three-dimensional channel systems. These phases are closely related to the zeolite- like M<sub>3</sub>Zn<sub>4</sub>O(XO<sub>4</sub>)<sub>3</sub>&middot;nH<sub>2</sub>O family of phases. Crystal data for (CH<sub>3</sub>NH<sub>3</sub>)<sub>3</sub>&middot;Zn<sub>4</sub>0(AsO<sub>4</sub>)<sub>3</sub>, M, = 790.47, monoclinic, space group P2<sub>1</sub> (No. 4), a = 7.814 (3)&Aring;, b = 15.498 (6)&Aring;, c = 7.815 (3) &Aring;, {beta} = 92.91 (2)0, V = 945.1 (9) &Aring;<sup>3</sup>, Z = 2, R(F) = 3.01%, R<sub>W</sub>(F) = 3.98% (2301 reflections, 236 parameters). Crystal data for (CH<sub>3</sub>NH<sub>3</sub>)<sub>3</sub>&middot;Zn<sub>4</sub>0(P0<sub>4</sub>)<sub>3</sub>: M, = ... continued below

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Chavez, Alejandra V.; Harrison, William T.A.; Nenoff, Tina M. & Phillips, Mark L.F. May 7, 1999.

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  • Sandia National Laboratories
    Publisher Info: Sandia National Laboratories (SNL), Albuquerque, NM, and Livermore, CA
    Place of Publication: Albuquerque, New Mexico

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The solution-mediated syntheses and single crystal structures of (CH<sub>3</sub>NH<sub>3</sub>)<sub>3</sub>&middot;Zn<sub>4</sub>0(AsO<sub>4</sub>)<sub>3</sub> and (CH<sub>3</sub>NH<sub>3</sub>)<sub>3</sub>&middot;Zn<sub>4</sub>O(P0<sub>4</sub>)<sub>3</sub> are reported. These compounds are built up from vertex-sharing three-dimensional Zn0<sub>4</sub> + AsO<sub>4</sub>/P0<sub>4</sub> tetrahedral frameworks encapsulating methylammonium cations in three-dimensional channel systems. These phases are closely related to the zeolite- like M<sub>3</sub>Zn<sub>4</sub>O(XO<sub>4</sub>)<sub>3</sub>&middot;nH<sub>2</sub>O family of phases. Crystal data for (CH<sub>3</sub>NH<sub>3</sub>)<sub>3</sub>&middot;Zn<sub>4</sub>0(AsO<sub>4</sub>)<sub>3</sub>, M, = 790.47, monoclinic, space group P2<sub>1</sub> (No. 4), a = 7.814 (3)&Aring;, b = 15.498 (6)&Aring;, c = 7.815 (3) &Aring;, {beta} = 92.91 (2)0, V = 945.1 (9) &Aring;<sup>3</sup>, Z = 2, R(F) = 3.01%, R<sub>W</sub>(F) = 3.98% (2301 reflections, 236 parameters). Crystal data for (CH<sub>3</sub>NH<sub>3</sub>)<sub>3</sub>&middot;Zn<sub>4</sub>0(P0<sub>4</sub>)<sub>3</sub>: M, = 658.63, monoclinic, space group P2<sub>1</sub> (No. 4), a = 7.6569 (5) &Aring;, b = 15.241 (1)&Aring;, c= 7.6589 (5) &Aring;, {beta} = 92.740 (1)0, V= 892.7 (5) &Aring;<sup>3</sup>, Z = 2, R(F)= 8.07%, R<sub>W</sub>(F)= 9.60% (2694 reflections, 106 parameters).

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  • Journal Name: Chemistry of Materials

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  • Other: DE00007048
  • Report No.: SAND99-1230J
  • Grant Number: AC04-94AL85000
  • Office of Scientific & Technical Information Report Number: 7048
  • Archival Resource Key: ark:/67531/metadc702266

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  • May 7, 1999

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Chavez, Alejandra V.; Harrison, William T.A.; Nenoff, Tina M. & Phillips, Mark L.F. Syntheses and Structures of the Open-Framework Phases (CH(3)NH(3))(3).Zn(4)O(AsO(4))(3) and (CH(3)NH(3))(3).Zn(4)O(PO(4))(3) Related to the M(3)Zn(4)O(XO(4)(3).nH(2)O Family, article, May 7, 1999; Albuquerque, New Mexico. (digital.library.unt.edu/ark:/67531/metadc702266/: accessed May 23, 2018), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.