Abraham Model Correlations for Solute Transfer into 2-Ethoxyethanol from Water and from the Gas Phase

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Article on Abraham model correlations for solute transfer into 2-ethoxyethanol from water and from the gas phase.

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8 p.

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Sedov, Igor A.; Stolov, Mikhail; Hart, Erin; Grover, Damini; Zettl, Heidi; Koshevarova, Victoria et al. August 1, 2015.

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Article on Abraham model correlations for solute transfer into 2-ethoxyethanol from water and from the gas phase.

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8 p.

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Abstract: Infinite dilution activity coefficients (γ∞) were measured at 298 K for 13 different aliphatic hydrocarbons (alkanes, cycloalkanes, alkenes), 12 different aromatic compounds (benzene, alkylbenzenes, halobenzenes, naphthalene), and 2-chloro-2-methylpropane dissolved in 2-ethoxyethanol, along with solubilities for 11 crystalline organic compounds (xanthene, phenothiazine, acenaphthene, diphenyl sulfone, 3,5-dinitro-2-methylbenzoic acid, 3-chlorobenzoic acid, 2-methylbenzoic acid, 4-chloro-3-nitrobenzoic acid, 3,5-dinitrobenzoic acid, benzil, and thioxanthen-9-one) dissolved in 2-ethoxyethanol at 298 K. The experimental values were converted to gas-to-2-ethoxyethanol partition coefficients, water-to-2-ethoxyethanol partition coefficients, and molar solubility ratios using standard thermodynamic relationships. The calculated partition coefficient data and molar solubility ratios, combined with published literature values, were used to derive Abraham model correlations for solute transfer into 2-ethoxyethanol from both water and the gas phase. The derived Abraham model correlations predicted the observed values to within 0.15 log units (or less).

This is the accepted manuscript version of the article. Reprinted with permission from Elsevier Science Ltd., all rights reserved. The final definitive version is available here: http://www.sciencedirect.com/science/article/pii/S016773221530009X

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  • Journal of Molecular Liquids, 2015, New York: Elsevier Science Ltd., pp. 63-70

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  • Publication Title: Journal of Molecular Liquids
  • Volume: 208
  • Page Start: 63
  • Page End: 70
  • Pages: 8
  • Peer Reviewed: Yes

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  • August 1, 2015

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  • Sept. 4, 2015, 1:25 p.m.

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  • June 7, 2017, 4:38 p.m.

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Sedov, Igor A.; Stolov, Mikhail; Hart, Erin; Grover, Damini; Zettl, Heidi; Koshevarova, Victoria et al. Abraham Model Correlations for Solute Transfer into 2-Ethoxyethanol from Water and from the Gas Phase, article, August 1, 2015; [New York, New York]. (digital.library.unt.edu/ark:/67531/metadc701857/: accessed December 14, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT College of Arts and Sciences.