Abraham Model Correlations for Estimating Solute Transfer of Neutral Molecules into Anhydrous Acetic Acid from Water and from the Gas Phase

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Article on Abraham model correlations for estimating solute transfer of neutral molecules into anhydrous acetic acid from water and from the gas phase.

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7 p.

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Stovall, Dawn M.; Schmidt, Amber; Dai, Colleen; Zhang, Shoshana; Acree, William E. (William Eugene) & Abraham, M. H. (Michael H.) September 1, 2015.

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Article on Abraham model correlations for estimating solute transfer of neutral molecules into anhydrous acetic acid from water and from the gas phase.

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7 p.

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Abstract: Experimental infinite dilution activity coefficient data, gas-to-liquid partition coefficient data, and solubility data have been combined from the published literature for neutral organic molecules and inert gases dissolved in anhydrous acetic acid (P) and gas-to-acetic acid (K) using standard thermodynamic relationships. The derived Abraham model correlations described the observed solubility and partition coefficient data of neutral organic compounds to within 0.18 log units (or less). Our analysis further showed that acetic acid solvent has considerable hydrogen-bond acidity, in agreement with the proposed linear structure for the solvent, and in terms of solubility related properties is not an unusual solvent at all.

This is the accepted manuscript version of the article. Reprinted with permission from Elsevier Science Ltd., all rights reserved.

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  • Journal of Molecular Liquids, 2015, New York: Elsevier Science Ltd., pp. 16-22

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  • Publication Title: Journal of Molecular Liquids
  • Volume: 212
  • Page Start: 16
  • Page End: 22
  • Pages: 7
  • Peer Reviewed: Yes

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  • September 1, 2015

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  • July 8, 2015

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  • August 18, 2015

Added to The UNT Digital Library

  • Sept. 4, 2015, 1:25 p.m.

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  • Sept. 4, 2015, 1:53 p.m.

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Stovall, Dawn M.; Schmidt, Amber; Dai, Colleen; Zhang, Shoshana; Acree, William E. (William Eugene) & Abraham, M. H. (Michael H.). Abraham Model Correlations for Estimating Solute Transfer of Neutral Molecules into Anhydrous Acetic Acid from Water and from the Gas Phase, article, September 1, 2015; [New York, New York]. (digital.library.unt.edu/ark:/67531/metadc701838/: accessed August 21, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT College of Arts and Sciences.