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Article on temperature and pressure dependence of the reaction S + CS (+M) → CS2 (+M).
Physical Description
5 p.
Notes
Reprinted with permission from the Journal of Physical Chemistry A. Copyright 2015 American Chemical Society.
Abstract: Experimental data for the unimolecular decomposition of CS2 from the literature are analyzed by unimolecular rate theory with the goal of obtaining rate constants for the reverse reaction S + CS (+M) → CS2 (+M) over wide temperature and pressure ranges. The results constitute an important input for the kinetic modeling of CS2 oxidation. CS2 dissociation proceeds as a spin-forbidden process whose detailed properties are still not well understood. The role of the singlet–triplet transition involved is discussed.
This article is part of the 100 Years of Combustion Kinetics at Argonne: A Festschrift for Lawrence B. Harding, Joe V. Michael, and Albert F. Wagner special issue.
Publication Title:
Journal of Physical Chemistry A
Volume:
119
Issue:
28
Page Start:
7277
Page End:
7281
Peer Reviewed:
Yes
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Glarborg, Peter; Marshall, Paul & Troe, Jürgen.Temperature and Pressure Dependence of the Reaction S + CS (+M) → CS2 (+M),
article,
January 27, 2015;
[Washington, D.C.].
(https://digital.library.unt.edu/ark:/67531/metadc699782/:
accessed April 25, 2024),
University of North Texas Libraries, UNT Digital Library, https://digital.library.unt.edu;
crediting UNT College of Arts and Sciences.