Intermediate- and extended-range order in phosphate glasses

PDF Version Also Available for Download.

Description

The structure of sodium ultraphosphate glasses, (Na{sub 2}O){sub x}(P{sub 2}O{sub 5}){sub 100-x} (x = 0, 10, 20), and alkali metaphosphate glasses, MePO{sub 3} (Me = Li, Na, K, Rb and Cs) have been studied by neutron diffraction. Structural features in the neutron structure factors S(Q) characteristic of intermediate-range (Q {approx_lt} 3 {angstrom}{sup -1}) order were identified. The feature of intermediate-range order in the pure phosphate glass (v-P{sub 2}O{sub 5}) is accounted for by the P{sub 4}O{sub 10} molecule packing model. The addition of the alkali metal modifier, Na, has drastic affect on the intermediate-range structure due to destruction of the ... continued below

Physical Description

21 p.

Creation Information

Suzuya, Kentaro; Price, D.L.; Loong, Chun-Keung & Martin, S.W. August 1, 1997.

Context

This article is part of the collection entitled: Office of Scientific & Technical Information Technical Reports and was provided by UNT Libraries Government Documents Department to Digital Library, a digital repository hosted by the UNT Libraries. More information about this article can be viewed below.

Who

People and organizations associated with either the creation of this article or its content.

Authors

Sponsors

Publisher

Provided By

UNT Libraries Government Documents Department

Serving as both a federal and a state depository library, the UNT Libraries Government Documents Department maintains millions of items in a variety of formats. The department is a member of the FDLP Content Partnerships Program and an Affiliated Archive of the National Archives.

Contact Us

What

Descriptive information to help identify this article. Follow the links below to find similar items on the Digital Library.

Description

The structure of sodium ultraphosphate glasses, (Na{sub 2}O){sub x}(P{sub 2}O{sub 5}){sub 100-x} (x = 0, 10, 20), and alkali metaphosphate glasses, MePO{sub 3} (Me = Li, Na, K, Rb and Cs) have been studied by neutron diffraction. Structural features in the neutron structure factors S(Q) characteristic of intermediate-range (Q {approx_lt} 3 {angstrom}{sup -1}) order were identified. The feature of intermediate-range order in the pure phosphate glass (v-P{sub 2}O{sub 5}) is accounted for by the P{sub 4}O{sub 10} molecule packing model. The addition of the alkali metal modifier, Na, has drastic affect on the intermediate-range structure due to destruction of the PO{sub 4} network structure. Around x {approximately} 50 a new peak arises at lower Q than the intermediate-range order peak, which is found in the S(Q)`s of all alkali metaphosphate glasses, associated with extended-range order. The length scale of extended-range order increases with Me{sup +} size. These phenomena can be explained by the behavior of oxygen atoms. i.e. PO{sub 4} chain-like units ordering around the Me{sup +}.

Physical Description

21 p.

Notes

OSTI as DE98000650

Source

  • 7. international conference on the structure of non-crystalline materials, Laguna (Italy), 15-19 Sep 1997

Language

Item Type

Identifier

Unique identifying numbers for this article in the Digital Library or other systems.

  • Other: DE98000650
  • Report No.: ANL/MSD/CP--94552
  • Report No.: CONF-9709101--
  • Grant Number: W-31109-ENG-38
  • Office of Scientific & Technical Information Report Number: 539889
  • Archival Resource Key: ark:/67531/metadc696016

Collections

This article is part of the following collection of related materials.

Office of Scientific & Technical Information Technical Reports

What responsibilities do I have when using this article?

When

Dates and time periods associated with this article.

Creation Date

  • August 1, 1997

Added to The UNT Digital Library

  • Aug. 14, 2015, 8:43 a.m.

Description Last Updated

  • Aug. 23, 2016, 3:08 p.m.

Usage Statistics

When was this article last used?

Yesterday: 0
Past 30 days: 0
Total Uses: 5

Interact With This Article

Here are some suggestions for what to do next.

Start Reading

PDF Version Also Available for Download.

Citations, Rights, Re-Use

Suzuya, Kentaro; Price, D.L.; Loong, Chun-Keung & Martin, S.W. Intermediate- and extended-range order in phosphate glasses, article, August 1, 1997; Illinois. (digital.library.unt.edu/ark:/67531/metadc696016/: accessed August 20, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.