Production of hydrogen by thermocatalytic cracking of natural gas. Task 4 report; Annual report

PDF Version Also Available for Download.

Description

The conventional methods of hydrogen production from natural gas, for example, steam reforming (SR), are complex multi-step processes. These processes also result in the emission of large quantities of CO{sub 2} into the atmosphere. One alternative is the single-step thermocatalytic cracking (TCC) (or decomposition) of natural gas into hydrogen and carbon. The comparative assessment of SR and TCC processes was conducted. Thermocatalytic cracking of methane over various catalysts and supports in a wide range of temperatures (500--900 C) and flow rates was conducted. Two types of fix bed catalytic reactors were designed, built and tested: continuous flow and pulse reactors. ... continued below

Physical Description

25 p.

Creation Information

Creator: Unknown. October 1, 1995.

Context

This report is part of the collection entitled: Office of Scientific & Technical Information Technical Reports and was provided by UNT Libraries Government Documents Department to Digital Library, a digital repository hosted by the UNT Libraries. More information about this report can be viewed below.

Who

People and organizations associated with either the creation of this report or its content.

Creator

  • We've been unable to identify the creator(s) of this report.

Sponsor

Publisher

Provided By

UNT Libraries Government Documents Department

Serving as both a federal and a state depository library, the UNT Libraries Government Documents Department maintains millions of items in a variety of formats. The department is a member of the FDLP Content Partnerships Program and an Affiliated Archive of the National Archives.

Contact Us

What

Descriptive information to help identify this report. Follow the links below to find similar items on the Digital Library.

Description

The conventional methods of hydrogen production from natural gas, for example, steam reforming (SR), are complex multi-step processes. These processes also result in the emission of large quantities of CO{sub 2} into the atmosphere. One alternative is the single-step thermocatalytic cracking (TCC) (or decomposition) of natural gas into hydrogen and carbon. The comparative assessment of SR and TCC processes was conducted. Thermocatalytic cracking of methane over various catalysts and supports in a wide range of temperatures (500--900 C) and flow rates was conducted. Two types of fix bed catalytic reactors were designed, built and tested: continuous flow and pulse reactors. Ni-Mo/Alumina and Fe-catalysts demonstrated relatively high efficiency in the methane cracking reaction at the range of temperatures 600--800 C. Fe-catalyst demonstrated fairly good stability, whereas alumina-supported Pt-catalyst rapidly lost its catalytic activity. Methane decomposition reaction over Ni-Mo/alumina was studied over wide range of space velocities in a continuous flow fixed bed catalytic reactor. The experimental results indicate that the hydrogen yield decreases noticeably with an increase in the space velocity of methane. The pulse type catalytic reactor was used to test the activity of the catalysts. It was found that induction period on the kinetic curve of hydrogen production corresponded to the reduction of metal oxide to metallic form of the catalyst. SEM method was used to study the structure of the carbon deposited on the catalyst surface.

Physical Description

25 p.

Notes

OSTI as DE98002552

Source

  • Other Information: PBD: Oct 1995

Language

Item Type

Identifier

Unique identifying numbers for this report in the Digital Library or other systems.

  • Other: DE98002552
  • Report No.: DOE/AL/85802--T2-Pt.4
  • Report No.: FSEC-CR--857-95-Pt.4
  • Grant Number: FG04-94AL85802
  • DOI: 10.2172/564093 | External Link
  • Office of Scientific & Technical Information Report Number: 564093
  • Archival Resource Key: ark:/67531/metadc694503

Collections

This report is part of the following collection of related materials.

Office of Scientific & Technical Information Technical Reports

Reports, articles and other documents harvested from the Office of Scientific and Technical Information.

Office of Scientific and Technical Information (OSTI) is the Department of Energy (DOE) office that collects, preserves, and disseminates DOE-sponsored research and development (R&D) results that are the outcomes of R&D projects or other funded activities at DOE labs and facilities nationwide and grantees at universities and other institutions.

What responsibilities do I have when using this report?

When

Dates and time periods associated with this report.

Creation Date

  • October 1, 1995

Added to The UNT Digital Library

  • Aug. 14, 2015, 8:43 a.m.

Description Last Updated

  • Nov. 13, 2015, 10:45 p.m.

Usage Statistics

When was this report last used?

Yesterday: 0
Past 30 days: 0
Total Uses: 8

Interact With This Report

Here are some suggestions for what to do next.

Start Reading

PDF Version Also Available for Download.

Citations, Rights, Re-Use

Production of hydrogen by thermocatalytic cracking of natural gas. Task 4 report; Annual report, report, October 1, 1995; United States. (digital.library.unt.edu/ark:/67531/metadc694503/: accessed December 18, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.