The Role of Oxygen in the Copper-Catalyzed Decomposition of Phenylborates in Aqueous Alkaline Solutions

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Description

The effect of oxygen on the copper-catalyzed hydrolysis of phenyl borates containing from one to four phenyl groups was studied in 1 M aqueous sodium hydroxide solution at 59 degrees C. The results are tentatively explained if the effective catalyst for each of the reactions is either cupric or cuprous ion, with the latter being present in significant concentration only in the absence of air.

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22 p.

Creation Information

Hyder, M.L. March 17, 1997.

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This report is part of the collection entitled: Office of Scientific & Technical Information Technical Reports and was provided by UNT Libraries Government Documents Department to Digital Library, a digital repository hosted by the UNT Libraries. More information about this report can be viewed below.

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  • Hyder, M.L. Westinghouse Savannah River Company, AIKEN, SC (United States)

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Description

The effect of oxygen on the copper-catalyzed hydrolysis of phenyl borates containing from one to four phenyl groups was studied in 1 M aqueous sodium hydroxide solution at 59 degrees C. The results are tentatively explained if the effective catalyst for each of the reactions is either cupric or cuprous ion, with the latter being present in significant concentration only in the absence of air.

Physical Description

22 p.

Notes

OSTI as DE98052142

Source

  • Other Information: PBD: 17 Mar 1997

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  • Other: DE98052142
  • Report No.: WSRC-TR--97-0069
  • Grant Number: AC09-96SR18500
  • DOI: 10.2172/585000 | External Link
  • Office of Scientific & Technical Information Report Number: 585000
  • Archival Resource Key: ark:/67531/metadc690974

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Creation Date

  • March 17, 1997

Added to The UNT Digital Library

  • Aug. 14, 2015, 8:43 a.m.

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  • Feb. 9, 2016, 8:58 p.m.

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Hyder, M.L. The Role of Oxygen in the Copper-Catalyzed Decomposition of Phenylborates in Aqueous Alkaline Solutions, report, March 17, 1997; Aiken, South Carolina. (digital.library.unt.edu/ark:/67531/metadc690974/: accessed September 21, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.