Preliminary results on the hydrolysis and carbonate complexation of dioxoplutonium(V)

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Description

The hydrolysis and carbonate complexation reactions of dioxoplutonium (V) were studied in near neutral aqueous systems. These experiments involved the addition of hydroxide or carbonate to Pu(V) in a perchorate medium. Change in the electronic adsorption spectra provided information about the chemical properties of Pu(V). The results indicate the Pu(V) does not hydrolyze below pH 7.15. In the carbonate complexation studies, log {beta}{sub 11} was measured to be 4.4 +- 0.7. 5 figs., 3 tabs.

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22 p.

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Bennett, D.A.; Hoffman, D.C.; Nitsche, H. & Silva, R.J. November 1, 1987.

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Description

The hydrolysis and carbonate complexation reactions of dioxoplutonium (V) were studied in near neutral aqueous systems. These experiments involved the addition of hydroxide or carbonate to Pu(V) in a perchorate medium. Change in the electronic adsorption spectra provided information about the chemical properties of Pu(V). The results indicate the Pu(V) does not hydrolyze below pH 7.15. In the carbonate complexation studies, log {beta}{sub 11} was measured to be 4.4 +- 0.7. 5 figs., 3 tabs.

Physical Description

22 p.

Notes

NTIS, PC A03; OSTI as DE88004444

Source

  • 194. American Chemical Society national meeting, New Orleans, LA (United States), 30 Aug - 4 Sep 1987

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  • Other: DE88004444
  • Report No.: LBL--24254
  • Report No.: CONF-870802--37
  • Grant Number: AC03-76SF00098
  • Office of Scientific & Technical Information Report Number: 60363
  • Archival Resource Key: ark:/67531/metadc690120

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  • November 1, 1987

Added to The UNT Digital Library

  • Aug. 14, 2015, 8:43 a.m.

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  • Aug. 1, 2016, 12:58 p.m.

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Bennett, D.A.; Hoffman, D.C.; Nitsche, H. & Silva, R.J. Preliminary results on the hydrolysis and carbonate complexation of dioxoplutonium(V), article, November 1, 1987; California. (digital.library.unt.edu/ark:/67531/metadc690120/: accessed August 19, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.