Novel approaches to the production of higher alcohols from synthesis gas. Quarterly technical progress report No. 19, April 1, 1995--June 30, 1995

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Three runs were carried out in the continuous stirred autoclave reactor with Englehard Zn-0312 T 1/8 {open_quotes}zinc chromite{close_quotes} catalyst and with decahydronaphthalene (Decalin{reg_sign}) as the slurry liquid. One short run, which was prematurely terminated by operational problems, was designed to define the effect of stirrer speed on catalyst performance. Two longer runs completed the data base required for kinetic characterization of the unpromoted {open_quotes}zinc chromite{close_quotes} catalyst. Although analysis of the data is not complete, it is evident that: (1) stirrer speed has no significant effect on the measured reaction rate, and; (2) carbon dioxide appears to inhibit catalyst activity.

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16 p.

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Roberts, G. W. October 10, 1996.

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Description

Three runs were carried out in the continuous stirred autoclave reactor with Englehard Zn-0312 T 1/8 {open_quotes}zinc chromite{close_quotes} catalyst and with decahydronaphthalene (Decalin{reg_sign}) as the slurry liquid. One short run, which was prematurely terminated by operational problems, was designed to define the effect of stirrer speed on catalyst performance. Two longer runs completed the data base required for kinetic characterization of the unpromoted {open_quotes}zinc chromite{close_quotes} catalyst. Although analysis of the data is not complete, it is evident that: (1) stirrer speed has no significant effect on the measured reaction rate, and; (2) carbon dioxide appears to inhibit catalyst activity.

Physical Description

16 p.

Notes

OSTI as DE97050482

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  • Other Information: PBD: 10 Oct 1996

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  • Other: DE97050482
  • Report No.: DOE/PC/90043--T20
  • Grant Number: AC22-90PC90043
  • DOI: 10.2172/415341 | External Link
  • Office of Scientific & Technical Information Report Number: 415341
  • Archival Resource Key: ark:/67531/metadc682769

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  • October 10, 1996

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  • July 25, 2015, 2:20 a.m.

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  • April 10, 2018, 7:14 p.m.

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Roberts, G. W. Novel approaches to the production of higher alcohols from synthesis gas. Quarterly technical progress report No. 19, April 1, 1995--June 30, 1995, report, October 10, 1996; Raleigh, North Carolina. (digital.library.unt.edu/ark:/67531/metadc682769/: accessed August 15, 2018), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.