Ion kinetics and thermodynamics pertinent to mass spectrometric organic speciation. Final report

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Description

Essentially all of the completed/in progress studies during the last contract period have involved the NIST HPMS unit. Three distinct areas of in-house research are recognizable: (i) determinations of binding energies and entropies for association and cluster ions, which is accomplished by measuring the temperature dependence of the appropriate equilibrium, (ii) measurement of the temperature dependence unimolecular and bimolecular rate constants, and (iii) evaluation of PA`s, HA`s, and IP`s via measurement of variable-temperature equilibria of the type AH{sup +} + B {longleftrightarrow} BH{sup +} + A, A{sup {minus}} + BH {longleftrightarrow} AH + B{sup {minus}}, and A{sup +} + B ... continued below

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11 p.

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Sieck, L.W. December 31, 1995.

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Description

Essentially all of the completed/in progress studies during the last contract period have involved the NIST HPMS unit. Three distinct areas of in-house research are recognizable: (i) determinations of binding energies and entropies for association and cluster ions, which is accomplished by measuring the temperature dependence of the appropriate equilibrium, (ii) measurement of the temperature dependence unimolecular and bimolecular rate constants, and (iii) evaluation of PA`s, HA`s, and IP`s via measurement of variable-temperature equilibria of the type AH{sup +} + B {longleftrightarrow} BH{sup +} + A, A{sup {minus}} + BH {longleftrightarrow} AH + B{sup {minus}}, and A{sup +} + B {longleftrightarrow} B{sup +} + A. Key results from some representative projects are summarized.

Physical Description

11 p.

Notes

OSTI as DE99002174

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  • Other Information: PBD: [1995]

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  • Other: DE99002174
  • Report No.: DOE/ER/14314--T3
  • Grant Number: AI02-93ER14314
  • DOI: 10.2172/334219 | External Link
  • Office of Scientific & Technical Information Report Number: 334219
  • Archival Resource Key: ark:/67531/metadc676777

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Creation Date

  • December 31, 1995

Added to The UNT Digital Library

  • July 25, 2015, 2:20 a.m.

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  • Nov. 5, 2015, 12:19 p.m.

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Sieck, L.W. Ion kinetics and thermodynamics pertinent to mass spectrometric organic speciation. Final report, report, December 31, 1995; United States. (digital.library.unt.edu/ark:/67531/metadc676777/: accessed September 23, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.