Amine-containing block copolymers: long-term adhesion promoters and corrosion resistant coatings

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Description

Arylamine-containing diblock copolymers were prepared via ring- opening metathesis polymerization (ROMP) to afford well-defined phase- separated materials. Alteration of the functionaity in a block, as well as the size of the blocks, allowed for the synthesis of self- assembled monolayers on a copper surface. The arylamine-containing block exhibited a strong binding affinity for the copper surface as seen by neutron reflectivity experiments. In addition, neutron reflectivity data verifies the self-assembly of block copolymer monolayers normal to the copper surface. Block copolymers prepared in this manner allow for the preparation of a wide range of adhesives and corrosion resistant materials. The ... continued below

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6 p.

Creation Information

Small, J.H.; Saunders, R.S. & Kent, M.S. July 1, 1996.

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This article is part of the collection entitled: Office of Scientific & Technical Information Technical Reports and was provided by UNT Libraries Government Documents Department to Digital Library, a digital repository hosted by the UNT Libraries. It has been viewed 36 times , with 4 in the last month . More information about this article can be viewed below.

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  • Sandia National Laboratories
    Publisher Info: Sandia National Labs., Albuquerque, NM (United States)
    Place of Publication: Albuquerque, New Mexico

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Description

Arylamine-containing diblock copolymers were prepared via ring- opening metathesis polymerization (ROMP) to afford well-defined phase- separated materials. Alteration of the functionaity in a block, as well as the size of the blocks, allowed for the synthesis of self- assembled monolayers on a copper surface. The arylamine-containing block exhibited a strong binding affinity for the copper surface as seen by neutron reflectivity experiments. In addition, neutron reflectivity data verifies the self-assembly of block copolymer monolayers normal to the copper surface. Block copolymers prepared in this manner allow for the preparation of a wide range of adhesives and corrosion resistant materials. The use of ring-opening metathesis polymerization is important because it permits the synthesis of a variety of functionalized block copolymers.

Physical Description

6 p.

Notes

OSTI as DE96011826

Source

  • 212. national meeting of the American Chemical Society (ACS), Orlando, FL (United States), 25-30 Aug 1996

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  • Other: DE96011826
  • Report No.: SAND--96-1357C
  • Report No.: CONF-960807--5
  • Grant Number: AC04-94AL85000
  • Office of Scientific & Technical Information Report Number: 273729
  • Archival Resource Key: ark:/67531/metadc673409

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Office of Scientific & Technical Information Technical Reports

Reports, articles and other documents harvested from the Office of Scientific and Technical Information.

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  • July 1, 1996

Added to The UNT Digital Library

  • June 29, 2015, 9:42 p.m.

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  • June 23, 2016, 1:17 p.m.

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Small, J.H.; Saunders, R.S. & Kent, M.S. Amine-containing block copolymers: long-term adhesion promoters and corrosion resistant coatings, article, July 1, 1996; Albuquerque, New Mexico. (digital.library.unt.edu/ark:/67531/metadc673409/: accessed April 24, 2018), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.