Volatility of copper

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Description

The relevant aqueous thermodynamics of copper and its oxides are evaluated and summarized with emphasis on solubility, hydrolysis, and complexation. The solubilities of metallic copper, solid cuprous and cupric oxides in steam measured by Pocock and Stewart in 1963 are discussed and the latter data are fitted in the form of established empirical equations and compared to other existing results. No other sources of data were found for the solubility of copper and cupric oxide in steam and even these data are very limited. Discussion of corresponding available solubility data on both oxide phases in liquid water is given. The ... continued below

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18 p.

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Palmer, D. A.; Simonson, J. M. & Joyce, D. B. August 1, 1996.

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This report is part of the collection entitled: Office of Scientific & Technical Information Technical Reports and was provided by UNT Libraries Government Documents Department to Digital Library, a digital repository hosted by the UNT Libraries. It has been viewed 45 times . More information about this report can be viewed below.

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Description

The relevant aqueous thermodynamics of copper and its oxides are evaluated and summarized with emphasis on solubility, hydrolysis, and complexation. The solubilities of metallic copper, solid cuprous and cupric oxides in steam measured by Pocock and Stewart in 1963 are discussed and the latter data are fitted in the form of established empirical equations and compared to other existing results. No other sources of data were found for the solubility of copper and cupric oxide in steam and even these data are very limited. Discussion of corresponding available solubility data on both oxide phases in liquid water is given. The possible effects of complexing agents are considered. A brief discussion is provided of the role of surface adsorption in determining the fate of dissolved copper in the boiler. 37 refs., 5 figs., 3 tabs.

Physical Description

18 p.

Notes

OSTI as DE96013463

Source

  • Interaction of non-iron based materials with water and steam conference, Piazena (Italy), 11-13 Jun 1996

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  • Other: DE96013463
  • Report No.: CONF-9606259--1
  • Grant Number: AC05-96OR22464
  • DOI: 10.2172/285269 | External Link
  • Office of Scientific & Technical Information Report Number: 285269
  • Archival Resource Key: ark:/67531/metadc670395

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Office of Scientific & Technical Information Technical Reports

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Office of Scientific and Technical Information (OSTI) is the Department of Energy (DOE) office that collects, preserves, and disseminates DOE-sponsored research and development (R&D) results that are the outcomes of R&D projects or other funded activities at DOE labs and facilities nationwide and grantees at universities and other institutions.

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Creation Date

  • August 1, 1996

Added to The UNT Digital Library

  • June 29, 2015, 9:42 p.m.

Description Last Updated

  • Oct. 3, 2017, 6:42 p.m.

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Palmer, D. A.; Simonson, J. M. & Joyce, D. B. Volatility of copper, report, August 1, 1996; Tennessee. (digital.library.unt.edu/ark:/67531/metadc670395/: accessed August 17, 2018), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.