Lithium: Thionyl chloride battery state-of-the-art assessment

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Description

Models of the performance of primary Li/SOCl{sub 2} cells can provide for realistic comparisons between technical information from different sources, and set standards that electronic circuit designers may refer to in the generation of high-quality products. Data from various investigators were used to derive mathematical- statistical relationships with physical design features (e.g. size and materials), operating parameters (e.g. current and temperature) and storage conditions (time and temperature). These efforts were substantially promoted by normalization procedures. For example, current loads were converted into current densities, or if appropriate, into current per unit cathode volume. Similarly, cell capacities were standardized with the ... continued below

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20 p.

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Eisenmann, E.T. March 1, 1996.

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This report is part of the collection entitled: Office of Scientific & Technical Information Technical Reports and was provided by UNT Libraries Government Documents Department to Digital Library, a digital repository hosted by the UNT Libraries. It has been viewed 51 times , with 6 in the last month . More information about this report can be viewed below.

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  • Sandia National Laboratories
    Publisher Info: Sandia National Labs., Albuquerque, NM (United States)
    Place of Publication: Albuquerque, New Mexico

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Description

Models of the performance of primary Li/SOCl{sub 2} cells can provide for realistic comparisons between technical information from different sources, and set standards that electronic circuit designers may refer to in the generation of high-quality products. Data from various investigators were used to derive mathematical- statistical relationships with physical design features (e.g. size and materials), operating parameters (e.g. current and temperature) and storage conditions (time and temperature). These efforts were substantially promoted by normalization procedures. For example, current loads were converted into current densities, or if appropriate, into current per unit cathode volume. Similarly, cell capacities were standardized with the maximum values observed at low current and also with respect to the cathode volume. Particular emphasis was placed on evaluations of voltage-delay, cell capacity and self-discharge, for which several equations were established. In spite of a considerable expenditure in time to find high-quality datasets, the reality is that all of the reviewed studies are flawed in one way or another. Specifically, all datasets are afflicted with sizable experimental errors and the precision of the regression equations is much lower than is deemed necessary for a universal model of the lithium thionyl chloride cell. Each of the equations has some definite truth content, but is generally incapable of bridging the gap between different studies. The basic failure to come up with a unifying model for Li/SOCl{sub 2} batteries leaves only one benefit of the present analysis, namely to provide guidance for future investigations. Several recommendations are made based on the insight gained during the search for good data in the relevant literature.

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20 p.

Notes

OSTI as DE96009202

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  • Other Information: PBD: Mar 1996

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  • Other: DE96009202
  • Report No.: SAND--96-0839
  • Grant Number: AC04-94AL85000
  • DOI: 10.2172/221912 | External Link
  • Office of Scientific & Technical Information Report Number: 221912
  • Archival Resource Key: ark:/67531/metadc668120

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Creation Date

  • March 1, 1996

Added to The UNT Digital Library

  • June 29, 2015, 9:42 p.m.

Description Last Updated

  • April 13, 2016, 2:46 p.m.

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Eisenmann, E.T. Lithium: Thionyl chloride battery state-of-the-art assessment, report, March 1, 1996; Albuquerque, New Mexico. (digital.library.unt.edu/ark:/67531/metadc668120/: accessed November 13, 2018), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.