The reactions of Na{sub 2} with O{sub 2}

PDF Version Also Available for Download.

Description

The reactions of Na{sub 2} with O{sub 2} were studied in a crossed-beam experiment at collision energies (E{sub c}) of 8 and 23 kcal/mol. The formation of NaO{sub 2} + Na was observed at both collision energies, with the angular distributions of NaO{sub 2} in the center of mass coordinates peaking strongly forward with respect to the direction of the O{sub 2} beam, suggesting that the reaction is completed in a time scale that is shorter than one rotational period of the molecular system. From the velocity distribution of the products, the authors found that the newly formed NaO{sub 2} ... continued below

Physical Description

27 p.

Creation Information

Hou, H.; Lu, K.T.; Sadchenko, V.; Suits, A.G. & Lee, Y.T. September 1, 1995.

Context

This report is part of the collection entitled: Office of Scientific & Technical Information Technical Reports and was provided by UNT Libraries Government Documents Department to Digital Library, a digital repository hosted by the UNT Libraries. More information about this report can be viewed below.

Who

People and organizations associated with either the creation of this report or its content.

Authors

Sponsor

Publisher

Provided By

UNT Libraries Government Documents Department

Serving as both a federal and a state depository library, the UNT Libraries Government Documents Department maintains millions of items in a variety of formats. The department is a member of the FDLP Content Partnerships Program and an Affiliated Archive of the National Archives.

Contact Us

What

Descriptive information to help identify this report. Follow the links below to find similar items on the Digital Library.

Description

The reactions of Na{sub 2} with O{sub 2} were studied in a crossed-beam experiment at collision energies (E{sub c}) of 8 and 23 kcal/mol. The formation of NaO{sub 2} + Na was observed at both collision energies, with the angular distributions of NaO{sub 2} in the center of mass coordinates peaking strongly forward with respect to the direction of the O{sub 2} beam, suggesting that the reaction is completed in a time scale that is shorter than one rotational period of the molecular system. From the velocity distribution of the products, the authors found that the newly formed NaO{sub 2} molecules are internally excited, with less than 20% of the available energy appearing in the translational motion of the separating products. These results indicate a ``spectator stripping`` mechanism for the reaction, with the O{sub 2} stripping one Na off the Na{sub 2} molecules. At E{sub c} = 23 kcal/mol the cross section for this reaction channel is estimated to be 0.8 {angstrom}{sup 2}. Another reaction channel which produces NaO + NaO was seen at E{sub c} = 23 kcal/mol. The angular distribution for NaO is broad and forward-backward symmetric in the center of mass frame. A substantial fraction of the available energy is released into the relative motion of the products. This reaction is likely to proceed on an excited potential energy surface since a charge transfer to the excited O{sub 2}{sup {minus}} orbitals seems necessary for breaking the O-O bond. The measurement yields a bond energy of 60 kcal/mol for the Na-O molecule, and a total cross section of 2 {angstrom}{sup 2} for this reaction channel at E{sub c} = 23 kcal/mol.

Physical Description

27 p.

Notes

OSTI as DE96005894

Source

  • Other Information: PBD: Sep 1995

Language

Item Type

Identifier

Unique identifying numbers for this report in the Digital Library or other systems.

  • Other: DE96005894
  • Report No.: LBL--37699
  • Grant Number: AC03-76SF00098
  • DOI: 10.2172/201703 | External Link
  • Office of Scientific & Technical Information Report Number: 201703
  • Archival Resource Key: ark:/67531/metadc667461

Collections

This report is part of the following collection of related materials.

Office of Scientific & Technical Information Technical Reports

Reports, articles and other documents harvested from the Office of Scientific and Technical Information.

Office of Scientific and Technical Information (OSTI) is the Department of Energy (DOE) office that collects, preserves, and disseminates DOE-sponsored research and development (R&D) results that are the outcomes of R&D projects or other funded activities at DOE labs and facilities nationwide and grantees at universities and other institutions.

What responsibilities do I have when using this report?

When

Dates and time periods associated with this report.

Creation Date

  • September 1, 1995

Added to The UNT Digital Library

  • June 29, 2015, 9:42 p.m.

Description Last Updated

  • April 5, 2016, 12:06 p.m.

Usage Statistics

When was this report last used?

Yesterday: 0
Past 30 days: 0
Total Uses: 3

Interact With This Report

Here are some suggestions for what to do next.

Start Reading

PDF Version Also Available for Download.

International Image Interoperability Framework

IIF Logo

We support the IIIF Presentation API

Hou, H.; Lu, K.T.; Sadchenko, V.; Suits, A.G. & Lee, Y.T. The reactions of Na{sub 2} with O{sub 2}, report, September 1, 1995; California. (digital.library.unt.edu/ark:/67531/metadc667461/: accessed October 17, 2018), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.