LDRD final report on gas separation by fullerene membranes

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Description

This LDRD (Laboratory Directed Research and Development) project was funded for two years beginning in October 1992 (FY93) and was designed as a multidisciplinary approach to determining the structural and physical properties of C{sub 60} intercalated with various gases. The purpose of the study was to evaluate the relative permeation and diffusion of various gases with an ultimate goal of finding an effective filter for gas separations. A variety of probes including NMR, X-ray and neutron diffraction; IR spectroscopy, thermogravimetric analysis and mass spectroscopy were employed on C{sub 60} impregnated with a number of gases including O{sub 2}, N{sub 2}, ... continued below

Physical Description

11 p.

Creation Information

Schirber, J.E.; Assink, R.A.; Morosin, B.; Loy, D.A. & Carlson, G.A. July 1, 1996.

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This report is part of the collection entitled: Office of Scientific & Technical Information Technical Reports and was provided by UNT Libraries Government Documents Department to Digital Library, a digital repository hosted by the UNT Libraries. More information about this report can be viewed below.

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  • Sandia National Laboratories
    Publisher Info: Sandia National Labs., Albuquerque, NM (United States)
    Place of Publication: Albuquerque, New Mexico

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Description

This LDRD (Laboratory Directed Research and Development) project was funded for two years beginning in October 1992 (FY93) and was designed as a multidisciplinary approach to determining the structural and physical properties of C{sub 60} intercalated with various gases. The purpose of the study was to evaluate the relative permeation and diffusion of various gases with an ultimate goal of finding an effective filter for gas separations. A variety of probes including NMR, X-ray and neutron diffraction; IR spectroscopy, thermogravimetric analysis and mass spectroscopy were employed on C{sub 60} impregnated with a number of gases including O{sub 2}, N{sub 2}, Ar, Ne, H{sub 2}, NO and CH{sub 4}. In order to increase the absorption and decrease the effective time constraints for bulk samples, these gases were intercalated into the C{sub 60} using pressures to several kbar. The results of these measurements which were quite encouraging for separation of O{sub 2} and N{sub 2} and for H{sub 2} from N{sub 2} led to 17 manuscripts which have been published in peer reviewed journals. The abstracts of these manuscripts are shown below along with a complete citation to the full text.

Physical Description

11 p.

Notes

OSTI as DE96013874

Source

  • Other Information: PBD: Jul 1996

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  • Other: DE96013874
  • Report No.: SAND--96-0584
  • Grant Number: AC04-94AL85000
  • DOI: 10.2172/270715 | External Link
  • Office of Scientific & Technical Information Report Number: 270715
  • Archival Resource Key: ark:/67531/metadc667410

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Office of Scientific & Technical Information Technical Reports

Reports, articles and other documents harvested from the Office of Scientific and Technical Information.

Office of Scientific and Technical Information (OSTI) is the Department of Energy (DOE) office that collects, preserves, and disseminates DOE-sponsored research and development (R&D) results that are the outcomes of R&D projects or other funded activities at DOE labs and facilities nationwide and grantees at universities and other institutions.

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Creation Date

  • July 1, 1996

Added to The UNT Digital Library

  • June 29, 2015, 9:42 p.m.

Description Last Updated

  • April 13, 2016, 2:44 p.m.

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Citations, Rights, Re-Use

Schirber, J.E.; Assink, R.A.; Morosin, B.; Loy, D.A. & Carlson, G.A. LDRD final report on gas separation by fullerene membranes, report, July 1, 1996; Albuquerque, New Mexico. (digital.library.unt.edu/ark:/67531/metadc667410/: accessed October 18, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.