Advanced thermally stable jet fuels. Technical progress report, April 1995--June 1995

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Description

Research continued on thermally stable jet fuel from coal liquids and petroleum distillates. The oxidative and thermal stabilities of ten fuels have been studied by differential scanning calorimetry and in microautoclave reactors. The compositions of the stressed fuels (as well as the unreacted fuels) were characterized by gas chromatography and gas chromatography/mass spectrometry. In addition, simulated distillation curves were determined by thermogravimetric analysis. The product distributions and reaction mechanisms for the thermal decomposition of n-alkanes in near-critical and supercritical regions were studied. The emphasis of the work in this reporting period has been placed on reaction mechanisms and product distributions. ... continued below

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122 p.

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Schobert, H.H.; Eser, S.; Boehman, A. & Song, C. August 1, 1995.

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Description

Research continued on thermally stable jet fuel from coal liquids and petroleum distillates. The oxidative and thermal stabilities of ten fuels have been studied by differential scanning calorimetry and in microautoclave reactors. The compositions of the stressed fuels (as well as the unreacted fuels) were characterized by gas chromatography and gas chromatography/mass spectrometry. In addition, simulated distillation curves were determined by thermogravimetric analysis. The product distributions and reaction mechanisms for the thermal decomposition of n-alkanes in near-critical and supercritical regions were studied. The emphasis of the work in this reporting period has been placed on reaction mechanisms and product distributions. Work is continuing on obtaining additional {sup 13}C-labeled jet fuel components for future thermal stressing studies. Compounds of current interest include 6-{sup 13}C-dodecane and 1-cyclohexyl-1-{sup 13}C-hexane. Further analysis of the formation of solids from the thermal stressing of decane and decalin has been performed.

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122 p.

Notes

OSTI as DE96012297

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  • Other Information: PBD: Aug 1995

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  • Other: DE96012297
  • Report No.: DOE/PC/92104--T12
  • Grant Number: FG22-92PC92104
  • DOI: 10.2172/251638 | External Link
  • Office of Scientific & Technical Information Report Number: 251638
  • Archival Resource Key: ark:/67531/metadc665632

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  • August 1, 1995

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  • June 29, 2015, 9:42 p.m.

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  • Nov. 18, 2015, 11:56 a.m.

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Schobert, H.H.; Eser, S.; Boehman, A. & Song, C. Advanced thermally stable jet fuels. Technical progress report, April 1995--June 1995, report, August 1, 1995; United States. (digital.library.unt.edu/ark:/67531/metadc665632/: accessed September 24, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.