Copper (II) Complexes with Deprotonated N-(2-hydroxyethyl)ethylenediamine

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Description

This thesis reports the synthesis and characterization of two new copper(II) halide complexes with deprotonated N-(2-hydroxyethyl)ethylenediamine behaving as a bidentate. The magnetic properties of the new copper(II) complexes were studied from room temperature to liquid nitrogen temperatures. The magnetic data show that both complexes exhibit antiferromagnetic interactions with a singlet ground state and a thermally accessible triplet excited state. Magnetic data and infrared spectra indicate the complexes are halogenbridged. Deprotonation at an amine nitrogen is based on the presence of a hydroxyl stretching band in the infrared spectra. Electronic spectra and infrared spectra indicate the complexes are square planar. Elemental ... continued below

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vi, 57 leaves: ill.

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Miller, Toney G. December 1975.

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  • Miller, Toney G.

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Description

This thesis reports the synthesis and characterization of two new copper(II) halide complexes with deprotonated N-(2-hydroxyethyl)ethylenediamine behaving as a bidentate. The magnetic properties of the new copper(II) complexes were studied from room temperature to liquid nitrogen temperatures. The magnetic data show that both complexes exhibit antiferromagnetic interactions with a singlet ground state and a thermally accessible triplet excited state. Magnetic data and infrared spectra indicate the complexes are halogenbridged. Deprotonation at an amine nitrogen is based on the presence of a hydroxyl stretching band in the infrared spectra. Electronic spectra and infrared spectra indicate the complexes are square planar. Elemental analyses, infrared spectra, electronic spectra, electron spin resonance spectra, and magnetic data are reported and discussed.

Physical Description

vi, 57 leaves: ill.

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UNT Theses and Dissertations

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  • December 1975

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  • June 24, 2015, 9:39 a.m.

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  • July 26, 2016, 11:49 a.m.

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Citations, Rights, Re-Use

Miller, Toney G. Copper (II) Complexes with Deprotonated N-(2-hydroxyethyl)ethylenediamine, thesis, December 1975; Denton, Texas. (digital.library.unt.edu/ark:/67531/metadc663729/: accessed January 20, 2018), University of North Texas Libraries, Digital Library, digital.library.unt.edu; .