Hydrogen adsorption on and solubility in graphites

PDF Version Also Available for Download.

Description

The experimental data on sorption and solubility of hydrogen isotopes in graphite in a wide ranges of temperature and pressure are reviewed. The Langmuir type adsorption is proposed for the hydrogen -- graphites interaction with taking into account dangling sp{sup 2}{minus}bonds relaxation. Three kinds of traps are proposed: Carbon interstitial loops with the adsorption enthalpy of {minus}4.4 eV/H{sub 2} (Traps l); carbon network edge atoms with the adsorption enthalpy of {minus}2.3 eV/H{sub 2} (Traps 2): Basal planes adsorption sites with enthalpy of +2.43 eV/H{sub 2} (Traps 3). The sorption capacity of every kind of graphite could be described with its ... continued below

Physical Description

5 p.

Creation Information

Kanashenko, S.L.; Gorodetsky, A.E.; Chernikov, V.N.; Markin, A.V. & Zakharov, A.P. December 1, 1995.

Context

This article is part of the collection entitled: Office of Scientific & Technical Information Technical Reports and was provided by UNT Libraries Government Documents Department to Digital Library, a digital repository hosted by the UNT Libraries. It has been viewed 12 times . More information about this article can be viewed below.

Who

People and organizations associated with either the creation of this article or its content.

Sponsor

Publisher

  • Sandia National Laboratories
    Publisher Info: Sandia National Labs., Albuquerque, NM (United States)
    Place of Publication: Albuquerque, New Mexico

Provided By

UNT Libraries Government Documents Department

Serving as both a federal and a state depository library, the UNT Libraries Government Documents Department maintains millions of items in a variety of formats. The department is a member of the FDLP Content Partnerships Program and an Affiliated Archive of the National Archives.

Contact Us

What

Descriptive information to help identify this article. Follow the links below to find similar items on the Digital Library.

Description

The experimental data on sorption and solubility of hydrogen isotopes in graphite in a wide ranges of temperature and pressure are reviewed. The Langmuir type adsorption is proposed for the hydrogen -- graphites interaction with taking into account dangling sp{sup 2}{minus}bonds relaxation. Three kinds of traps are proposed: Carbon interstitial loops with the adsorption enthalpy of {minus}4.4 eV/H{sub 2} (Traps l); carbon network edge atoms with the adsorption enthalpy of {minus}2.3 eV/H{sub 2} (Traps 2): Basal planes adsorption sites with enthalpy of +2.43 eV/H{sub 2} (Traps 3). The sorption capacity of every kind of graphite could be described with its own unique set of traps. The number of potential sites for the ``true solubility`` (Traps 3) we assume as 1E+6 appm, or HC=l, but endothermic character of this solubility leads to negligible amount of inventory in comparison with Traps 1 and Traps 2. The irradiation with neutrons or carbon atoms increases the number of Traps 1 and Traps 2. At damage level of {approximately}1 dpa under room temperature irradiation the number of these traps was increased up to 1500 and 5000 appm respectively. Traps 1 and Traps 2 are stable under high temperature annealing.

Physical Description

5 p.

Notes

OSTI as DE96002737

Source

  • Meeting of the Institute of Physical Chemistry of the Russian Academy of Sciences, Moscow (Russian Federation), 30 Sep - 6 Oct 1995

Language

Item Type

Identifier

Unique identifying numbers for this article in the Digital Library or other systems.

  • Other: DE96002737
  • Report No.: SAND--95-2484C
  • Report No.: CONF-9509258--1
  • Grant Number: AC04-94AL85000
  • Office of Scientific & Technical Information Report Number: 158463
  • Archival Resource Key: ark:/67531/metadc623619

Collections

This article is part of the following collection of related materials.

Office of Scientific & Technical Information Technical Reports

Reports, articles and other documents harvested from the Office of Scientific and Technical Information.

Office of Scientific and Technical Information (OSTI) is the Department of Energy (DOE) office that collects, preserves, and disseminates DOE-sponsored research and development (R&D) results that are the outcomes of R&D projects or other funded activities at DOE labs and facilities nationwide and grantees at universities and other institutions.

What responsibilities do I have when using this article?

When

Dates and time periods associated with this article.

Creation Date

  • December 1, 1995

Added to The UNT Digital Library

  • June 16, 2015, 7:43 a.m.

Description Last Updated

  • April 14, 2016, 7:47 p.m.

Usage Statistics

When was this article last used?

Yesterday: 0
Past 30 days: 0
Total Uses: 12

Interact With This Article

Here are some suggestions for what to do next.

Start Reading

PDF Version Also Available for Download.

Citations, Rights, Re-Use

Kanashenko, S.L.; Gorodetsky, A.E.; Chernikov, V.N.; Markin, A.V. & Zakharov, A.P. Hydrogen adsorption on and solubility in graphites, article, December 1, 1995; Albuquerque, New Mexico. (digital.library.unt.edu/ark:/67531/metadc623619/: accessed December 11, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.