Dissolution of two NWCF calcines: Extent of dissolution and characterization of undissolved solids

PDF Version Also Available for Download.

Description

A study was undertaken to determine the dissolution characteristics of two NWCF calcine types. A two-way blended calcine made from 4 parts nonradioactive aluminum nitrate and one part WM-102 was studied to determine the extent of dissolution for aluminum-type calcines. A two-way blend of 3.5 parts fluorinel waste from WM-187 and 1 part sodium waste from WM-185 was used to determine the extent of dissolution for zirconium-type calcines. This study was necessary to develop suitable aqueous separation flowsheets for the partitioning of actinides and fission products from ICPP calcines and to determine the disposition of the resulting undissolved solids (UDS). ... continued below

Physical Description

48 p.

Creation Information

Brewer, K.N.; Herbst, R.S. & Tranter, T.J. January 1, 1995.

Context

This report is part of the collection entitled: Office of Scientific & Technical Information Technical Reports and was provided by UNT Libraries Government Documents Department to Digital Library, a digital repository hosted by the UNT Libraries. More information about this report can be viewed below.

Who

People and organizations associated with either the creation of this report or its content.

Sponsor

Publisher

  • EG & G, Inc.
    Publisher Info: EG and G Idaho, Inc., Idaho Falls, ID (United States)
    Place of Publication: Idaho Falls, Idaho

Provided By

UNT Libraries Government Documents Department

Serving as both a federal and a state depository library, the UNT Libraries Government Documents Department maintains millions of items in a variety of formats. The department is a member of the FDLP Content Partnerships Program and an Affiliated Archive of the National Archives.

Contact Us

What

Descriptive information to help identify this report. Follow the links below to find similar items on the Digital Library.

Description

A study was undertaken to determine the dissolution characteristics of two NWCF calcine types. A two-way blended calcine made from 4 parts nonradioactive aluminum nitrate and one part WM-102 was studied to determine the extent of dissolution for aluminum-type calcines. A two-way blend of 3.5 parts fluorinel waste from WM-187 and 1 part sodium waste from WM-185 was used to determine the extent of dissolution for zirconium-type calcines. This study was necessary to develop suitable aqueous separation flowsheets for the partitioning of actinides and fission products from ICPP calcines and to determine the disposition of the resulting undissolved solids (UDS). The dissolution flowsheet developed by Herbst was used to dissolve these two NWCF calcine types. Results show that greater than 95 wt% of aluminum and zirconium calcine types were dissolved after a single batch contact with 5 M HNO{sub 3}. A characterization of the UDS indicates that the weight percent of TRU elements in the UDS resulting from both calcine type dissolutions increases by approximately an order of magnitude from their concentrations prior to dissolution. Substantial activities of cesium and strontium are also present in the UDS resulting from the dissolution of both calcine types. Multiple TRU, Cs, and Sr analyses of both UDS types show that these solids are relatively homogeneous. From this study, it is estimated that between 63.5 and 635 cubic meters of UDS will be generated from the dissolution of 3800 M{sub 3} of calcine. The significant actinide and fission product activities in these UDS will preclude their disposal as low-level waste. If the actinide and fission activity resulting from the UDS is the only considered source in the dissolved calcine solutions, an estimated 99.9 to 99.99 percent of the solids must be removed from this solution for it to meet non-TRU Class A low-level waste.

Physical Description

48 p.

Notes

INIS; OSTI as DE96004069

Source

  • Other Information: PBD: Jan 1995

Language

Item Type

Identifier

Unique identifying numbers for this report in the Digital Library or other systems.

  • Other: DE96004069
  • Report No.: INEL--95/0098
  • Grant Number: AC07-94ID13223
  • DOI: 10.2172/152645 | External Link
  • Office of Scientific & Technical Information Report Number: 152645
  • Archival Resource Key: ark:/67531/metadc621204

Collections

This report is part of the following collection of related materials.

Office of Scientific & Technical Information Technical Reports

Reports, articles and other documents harvested from the Office of Scientific and Technical Information.

Office of Scientific and Technical Information (OSTI) is the Department of Energy (DOE) office that collects, preserves, and disseminates DOE-sponsored research and development (R&D) results that are the outcomes of R&D projects or other funded activities at DOE labs and facilities nationwide and grantees at universities and other institutions.

What responsibilities do I have when using this report?

When

Dates and time periods associated with this report.

Creation Date

  • January 1, 1995

Added to The UNT Digital Library

  • June 16, 2015, 7:43 a.m.

Description Last Updated

  • April 26, 2016, 4:50 p.m.

Usage Statistics

When was this report last used?

Yesterday: 0
Past 30 days: 0
Total Uses: 6

Interact With This Report

Here are some suggestions for what to do next.

Start Reading

PDF Version Also Available for Download.

Citations, Rights, Re-Use

Brewer, K.N.; Herbst, R.S. & Tranter, T.J. Dissolution of two NWCF calcines: Extent of dissolution and characterization of undissolved solids, report, January 1, 1995; Idaho Falls, Idaho. (digital.library.unt.edu/ark:/67531/metadc621204/: accessed November 24, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.