Flash photolysis-shock tube studies.

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Following earlier investigations on the dissociation rates of halogen containing molecules, we studied the thermal decompositions of CHCl{sub 3} and CF{sub 3}Br. In addition, we measured the branching ratio and rate constants for the thermal decomposition of H{sub 2}CO. We studied three bimolecular rate processes: H + H{sub 2}CC0, CF{sub 3} + H{sub 2}, and H + CF{sub 3}H. Decomposition studies in reflected shock waves on three reactions were completed using atomic resonance absorption spectroscopic (ARAS) detection and/or the laser schlieren density gradient (LS) method.

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7 p.

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Michael, J. V. March 5, 1998.

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Description

Following earlier investigations on the dissociation rates of halogen containing molecules, we studied the thermal decompositions of CHCl{sub 3} and CF{sub 3}Br. In addition, we measured the branching ratio and rate constants for the thermal decomposition of H{sub 2}CO. We studied three bimolecular rate processes: H + H{sub 2}CC0, CF{sub 3} + H{sub 2}, and H + CF{sub 3}H. Decomposition studies in reflected shock waves on three reactions were completed using atomic resonance absorption spectroscopic (ARAS) detection and/or the laser schlieren density gradient (LS) method.

Physical Description

7 p.

Notes

OSTI as DE00011024

Medium: P; Size: 7 pages

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  • 20th Annual Combustion Research Conference, Dallas, TX (US), 03/29/1998--04/03/1998

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  • Report No.: ANL/CHM/CP-95779
  • Grant Number: W-31109-ENG-38
  • Office of Scientific & Technical Information Report Number: 11024
  • Archival Resource Key: ark:/67531/metadc620720

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  • March 5, 1998

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  • June 16, 2015, 7:43 a.m.

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  • April 11, 2017, 3:26 p.m.

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Michael, J. V. Flash photolysis-shock tube studies., article, March 5, 1998; Illinois. (digital.library.unt.edu/ark:/67531/metadc620720/: accessed September 24, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.