The experimental determination of the solubility product for NpO{sub 2}OH in NaCl solutions

PDF Version Also Available for Download.

Description

The solubility of Np(V) was measured in NaCl solutions ranging from 0.30 to 5.6 molal at room temperature ({approximately}21 {plus_minus} 2{degrees}C). Experiments were conducted from undersaturation and allowed to equilibrate in a CO{sub 2}-free environment for 37 days. The apparent solubility products varied with NaCl concentration and were between 10{sup -9} and 10{sup -8} mol{sup 2}{sm_bullet}L{sup -2}. Using the specific ion interaction theory (SIT), the log of the solubility product of NpO{sub 2}OH(am) at infinite dilution was found to be - 8.79 {plus_minus} 0.12. The interaction coefficient, {epsilon}(NpO{sub 2}{sup +} - Cl{sup -}), was found to be (0.08 {plus_minus} 0.05).

Physical Description

12 p.

Creation Information

Roberts, K.E.; Torretto, P.C. & Prussin, T. September 1, 1995.

Context

This article is part of the collection entitled: Office of Scientific & Technical Information Technical Reports and was provided by UNT Libraries Government Documents Department to Digital Library, a digital repository hosted by the UNT Libraries. More information about this article can be viewed below.

Who

People and organizations associated with either the creation of this article or its content.

Authors

Sponsor

Publisher

  • Sandia National Laboratories
    Publisher Info: Sandia National Labs., Albuquerque, NM (United States)
    Place of Publication: Albuquerque, New Mexico

Provided By

UNT Libraries Government Documents Department

Serving as both a federal and a state depository library, the UNT Libraries Government Documents Department maintains millions of items in a variety of formats. The department is a member of the FDLP Content Partnerships Program and an Affiliated Archive of the National Archives.

Contact Us

What

Descriptive information to help identify this article. Follow the links below to find similar items on the Digital Library.

Description

The solubility of Np(V) was measured in NaCl solutions ranging from 0.30 to 5.6 molal at room temperature ({approximately}21 {plus_minus} 2{degrees}C). Experiments were conducted from undersaturation and allowed to equilibrate in a CO{sub 2}-free environment for 37 days. The apparent solubility products varied with NaCl concentration and were between 10{sup -9} and 10{sup -8} mol{sup 2}{sm_bullet}L{sup -2}. Using the specific ion interaction theory (SIT), the log of the solubility product of NpO{sub 2}OH(am) at infinite dilution was found to be - 8.79 {plus_minus} 0.12. The interaction coefficient, {epsilon}(NpO{sub 2}{sup +} - Cl{sup -}), was found to be (0.08 {plus_minus} 0.05).

Physical Description

12 p.

Notes

INIS; OSTI as DE95017644

Source

  • 5. international conference on the chemistry and migration behaviour of actinides and fission products in the geosphere, Saint-Malo (France), 10-15 Sep 1995

Language

Item Type

Identifier

Unique identifying numbers for this article in the Digital Library or other systems.

  • Other: DE95017644
  • Report No.: SAND--95-2008C
  • Report No.: CONF-950946--4
  • Grant Number: AC04-94AL85000
  • Office of Scientific & Technical Information Report Number: 102399
  • Archival Resource Key: ark:/67531/metadc618878

Collections

This article is part of the following collection of related materials.

Office of Scientific & Technical Information Technical Reports

Reports, articles and other documents harvested from the Office of Scientific and Technical Information.

Office of Scientific and Technical Information (OSTI) is the Department of Energy (DOE) office that collects, preserves, and disseminates DOE-sponsored research and development (R&D) results that are the outcomes of R&D projects or other funded activities at DOE labs and facilities nationwide and grantees at universities and other institutions.

What responsibilities do I have when using this article?

When

Dates and time periods associated with this article.

Creation Date

  • September 1, 1995

Added to The UNT Digital Library

  • June 16, 2015, 7:43 a.m.

Description Last Updated

  • April 13, 2016, 1:49 p.m.

Usage Statistics

When was this article last used?

Yesterday: 0
Past 30 days: 0
Total Uses: 5

Interact With This Article

Here are some suggestions for what to do next.

Start Reading

PDF Version Also Available for Download.

Citations, Rights, Re-Use

Roberts, K.E.; Torretto, P.C. & Prussin, T. The experimental determination of the solubility product for NpO{sub 2}OH in NaCl solutions, article, September 1, 1995; Albuquerque, New Mexico. (digital.library.unt.edu/ark:/67531/metadc618878/: accessed November 19, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT Libraries Government Documents Department.