Deduction of physiochemical properties from solubilities: 2,4-dihydroxybenzophenone, biotin, and caprolactam as examples

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Article discussing the deduction of physiochemical properties from solubilities and 2,4-dihydroxybenzophenone, biotin, and caprolactam as examples.

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7 p.

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Abraham, M. H. (Michael H.); Acree, William E. (William Eugene); Brumfield, Michela; Hart, Erin; Pipersburgh, Lila; Mateja, Katherine et al. April 15, 2015.

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Article discussing the deduction of physiochemical properties from solubilities and 2,4-dihydroxybenzophenone, biotin, and caprolactam as examples.

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7 p.

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Abstract: Solubilities of 2,4-dihydroxybenzophenone have been measured at 298 K in 19 organic solvents. Combination with a known value of the solubility in water enables corresponding partition coefficients from water to these solvents to be deduced. It is shown that solubilities, via the partition coefficients, can yield the Abraham descriptors for 2,4-dihydroxybenzophenone, and that these, in turn, can be used to estimate a very large number of further solubilities, partition coefficients, and values of biological and environmental properties. This method of extracting information from solubilities is further illustrated using literature data on solubilities of biotin and of caprolactam.

Reprinted with permission from the Journal of Chemical and Engineering Data. Copyright 2015 American Chemical Society.

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  • Journal of Chemical and Engineering Data, 2015, Washington D.C.: American Chemical Society, pp. 1440-1446

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  • Publication Title: Journal of Chemical and Engineering Data
  • Volume: 60
  • Issue: 5
  • Page Start: 1440
  • Page End: 1446
  • Pages: 7
  • Peer Reviewed: Yes

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  • April 15, 2015

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  • December 16, 2014

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  • April 7, 2015

Added to The UNT Digital Library

  • May 29, 2015, 9:36 p.m.

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  • June 7, 2017, 4:37 p.m.

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Abraham, M. H. (Michael H.); Acree, William E. (William Eugene); Brumfield, Michela; Hart, Erin; Pipersburgh, Lila; Mateja, Katherine et al. Deduction of physiochemical properties from solubilities: 2,4-dihydroxybenzophenone, biotin, and caprolactam as examples, article, April 15, 2015; [Washington, D.C.]. (digital.library.unt.edu/ark:/67531/metadc505690/: accessed September 18, 2018), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT College of Arts and Sciences.