Kinetics of the Reaction of Atomic Oxygen with Tetramethylsilane

PDF Version Also Available for Download.

Description

Article on kinetics of the reaction of atomic oxygen with tetramethylsilane.

Physical Description

3 p.

Creation Information

Ding, Luying & Marshall, Paul April 1993.

Context

This article is part of the collection entitled: UNT Scholarly Works and was provided by UNT College of Arts and Sciences to Digital Library, a digital repository hosted by the UNT Libraries. It has been viewed 24 times . More information about this article can be viewed below.

Who

People and organizations associated with either the creation of this article or its content.

Authors

Publisher

Provided By

UNT College of Arts and Sciences

The UNT College of Arts and Sciences educates students in traditional liberal arts, performing arts, sciences, professional, and technical academic programs. In addition to its departments, the college includes academic centers, institutes, programs, and offices providing diverse courses of study.

Contact Us

What

Descriptive information to help identify this article. Follow the links below to find similar items on the Digital Library.

Degree Information

Description

Article on kinetics of the reaction of atomic oxygen with tetramethylsilane.

Physical Description

3 p.

Notes

Abstract: The rate constant for O(2p)³Pᴊ + (CH₃)₄Si has been measured using the flash photolysis/resonance fluorescence technique over the temperature range 380-700 K. The results are described by k = (5.1 ± 0.7) x 10⁻¹¹ exp(-24.1 ± 0.6 kJ mol⁻¹ /RT) cm³ s⁻¹ where the uncertainties represent ± 1σ precision. The 95% accuracy interval for k is about ± 15%. The results show that the activation energy Eₐ is reduced compared to other hydrocarbons by the trimethylsilyl group. A series of O + primary C-H bond reactions are considered, and possible correlations between Eₐ and the C-H bond energy and hydrocarbon ionization potential are discussed.

Reprinted with permission from the Journal of Physical Chemistry. Copyright 1993 American Chemical Society.

Source

  • Journal of Physical Chemistry, 1993, Washington D.C.: American Chemical Society, pp. 3758-3760

Language

Item Type

Identifier

Unique identifying numbers for this article in the Digital Library or other systems.

Publication Information

  • Publication Title: Journal of Physical Chemistry
  • Volume: 97
  • Issue: 15
  • Page Start: 3758
  • Page End: 3760
  • Pages: 3
  • Peer Reviewed: Yes

Collections

This article is part of the following collection of related materials.

UNT Scholarly Works

Materials from the UNT community's research, creative, and scholarly activities and UNT's Open Access Repository. Access to some items in this collection may be restricted.

What responsibilities do I have when using this article?

When

Dates and time periods associated with this article.

Creation Date

  • April 1993

Added to The UNT Digital Library

  • April 25, 2015, 8:59 p.m.

Usage Statistics

When was this article last used?

Yesterday: 0
Past 30 days: 1
Total Uses: 24

Interact With This Article

Here are some suggestions for what to do next.

Start Reading

PDF Version Also Available for Download.

Citations, Rights, Re-Use

Ding, Luying & Marshall, Paul. Kinetics of the Reaction of Atomic Oxygen with Tetramethylsilane, article, April 1993; [Washington, D.C.]. (digital.library.unt.edu/ark:/67531/metadc503236/: accessed September 20, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT College of Arts and Sciences.