Degradation Products of Tributyl Phosphate

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Description

Abstract: "A method for determination of dibutyl phosphate in solvent streams containing tributyl phosphate is outlined. The method is based on analysis for total uranium of total phosphate after removal of uranium and phosphate in excess of that present as uranyl dibutyl phosphate. Results on plant solvent samples are presented. Difficulties with precipitation of [...] dibutyl phosphate, when fresh solvents were employed, are discussed. Small amounts of nonphosphate uranium-complexing agents were found in plant solvents. Diluent degradation is postulated as the source of these components. Emulsion-formation tendencies appeared to correlate better with concentrations of these contaminants than with dibutyl phosphate … continued below

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[48] p. : tables ; 28 cm.

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Ewing, Robert A.; Kiehl, Samuel J. & Bearse, Arthur E. February 17, 1956.

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Abstract: "A method for determination of dibutyl phosphate in solvent streams containing tributyl phosphate is outlined. The method is based on analysis for total uranium of total phosphate after removal of uranium and phosphate in excess of that present as uranyl dibutyl phosphate. Results on plant solvent samples are presented. Difficulties with precipitation of [...] dibutyl phosphate, when fresh solvents were employed, are discussed. Small amounts of nonphosphate uranium-complexing agents were found in plant solvents. Diluent degradation is postulated as the source of these components. Emulsion-formation tendencies appeared to correlate better with concentrations of these contaminants than with dibutyl phosphate content."

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[48] p. : tables ; 28 cm.

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Digitized from microopaque cards (2).

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  • OCLC: 922552628
  • SuDoc Number: Y 3.AT 7:22/BMI-1073
  • Report No.: BMI-1073
  • Archival Resource Key: ark:/67531/metadc502934

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Technical Report Archive and Image Library

The Technical Report Archive & Image Library (TRAIL) identifies, acquires, catalogs, digitizes and provides unrestricted access to U.S. government agency technical reports. The mission of TRAIL is to ensure preservation, discoverability, and persistent open access to government technical publications regardless of form or format.

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Imaged from microcard, these technical reports describe research performed for U.S. government agencies from the 1930s to the 1960s. The reports were provided by the Technical Report Archive and Image Library (TRAIL).

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  • February 17, 1956

Added to The UNT Digital Library

  • Feb. 12, 2018, 7:42 a.m.

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  • April 23, 2019, 3:27 p.m.

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Ewing, Robert A.; Kiehl, Samuel J. & Bearse, Arthur E. Degradation Products of Tributyl Phosphate, report, February 17, 1956; Columbus, Ohio. (https://digital.library.unt.edu/ark:/67531/metadc502934/: accessed June 20, 2025), University of North Texas Libraries, UNT Digital Library, https://digital.library.unt.edu; crediting UNT Libraries Government Documents Department.

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