Determination of the Absolute Second-order Rate Constant for the Reaction Na + O₃ → NaO + O₂

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Article on the determination of the absolute second-order rate constant for the reaction Na + O₃ → NaO + O₂.

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3 p.

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Husain, David; Marshall, Paul & Plane, John M. C. 1985.

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Article on the determination of the absolute second-order rate constant for the reaction Na + O₃ → NaO + O₂.

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3 p.

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Abstract: The absolute second-order rate constant for the reaction Na + O₃ → NaO + O₂ (k₁) has been determined by time-resolved atomic resonance absorption spectroscopy at λ = 589 nm [Na(3²Pᴊ) ← Na(3²S1/2)] following pulsed irradiation, coupled with monitoring of O₃ by light absorption in the ultra-violet; this yields k₁(500 K) = 4 (+4, -2) x 10⁻¹⁰ cm³ molecule⁻¹ s⁻¹, resolving large differences for various estimates of this important quantity used in modelling the sodium layer in the mesosphere.

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  • Journal of the Chemical Society, Chemical Communications, 1985, Cambridge: Royal Society of Chemistry (Great Britain), pp. 1216-1218

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  • Publication Title: Journal of the Chemical Society, Chemical Communications
  • Issue: 18
  • Page Start: 1216
  • Page End: 1218
  • Pages: 3
  • Peer Reviewed: Yes

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  • 1985

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  • Jan. 22, 2015, 9:04 a.m.

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Husain, David; Marshall, Paul & Plane, John M. C. Determination of the Absolute Second-order Rate Constant for the Reaction Na + O₃ → NaO + O₂, article, 1985; [Cambridge, England]. (digital.library.unt.edu/ark:/67531/metadc488151/: accessed June 24, 2018), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT College of Arts and Sciences.