Thermodynamics of mobile order theory

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Article on the thermodynamics of mobile order theory.

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37 p.

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Acree, William E. (William Eugene); Powell, Joyce R.; McHale, Mary E. R.; Pandey, Siddharth; Borders, Tammie L. & Campbell, Scott W. 1997.

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Article on the thermodynamics of mobile order theory.

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37 p.

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Mobile order theory provides an alternative thermodynamic approach for mathematically describing associated solutions. The basic model expresses the equilibrium condition in terms of the time fractions for the time schedule that a given molecule in an ensemble is "free" or "bonded", and not in terms of the concentrations of the various associated species believed to be present. This review article discusses the thermodynamic basis of Mobile Order theory, and critically examines the model's applicability using published vapor-liquid equilibria (VLE), solid-liquid equilibria (SLE) and excess enthalpy data for binary and ternary systems containing alkane and alcohol cosolvents. Also presented is the application of Mobile Order theory to aqueous solubility predictions of crystalline organic nonelectrolyte solutes.

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  • Trends in Physical Chemistry, 1997, Kerala: Research Trends, pp. 197-233

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  • Publication Title: Trends in Physical Chemistry
  • Volume: 6
  • Page Start: 197
  • Page End: 233
  • Peer Reviewed: Yes

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  • 1997

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  • Oct. 23, 2014, 12:02 p.m.

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Acree, William E. (William Eugene); Powell, Joyce R.; McHale, Mary E. R.; Pandey, Siddharth; Borders, Tammie L. & Campbell, Scott W. Thermodynamics of mobile order theory, article, 1997; [Kerala, India]. (digital.library.unt.edu/ark:/67531/metadc406338/: accessed December 16, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT College of Arts and Sciences.