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Article on the characterization of room-temperature ionic liquids by the Abraham model with cation-specific and anion-specific equation coefficients.
Physical Description
7 p.
Notes
Abstract: Gas-to-RTIL (room-temperature ionic liquid) partition coefficients have been compiled for 592 different solute-RTIL combinations. These partition coefficients were converted into water-to-RTIL partition coefficients using the corresponding gas-to-water partition coefficients. Both sets of partition coefficients were analyzed using the Abraham solvation parameter model with cation-specific and anion-specific equation coefficients. The derived equations correlated the experimental gas-to-RTIL and water-to-RTIL partition coefficient data to within 0.10 and 0.14 log units, respectively. The 8 sets of calculated cation-specific equation coefficients and 4 sets of calculated anion-specific equation coefficients can be combined to yield expressions capable of predicting the partition coefficients of solutes in 32 different RTILs.
Reprinted with permission from the Journal of Chemical Information and Modeling. Copyright 2007 American Chemical Society.
Publication Title:
Journal of Chemical Information and Modeling
Volume:
47
Issue:
3
Page Start:
1123
Page End:
1129
Peer Reviewed:
Yes
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Sprunger, Laura M.; Clark, Michael; Acree, William E. (William Eugene) & Abraham, M. H. (Michael H.).Characterization of Room-Temperature Ionic Liquids by the Abraham Model with Cation-Specific and Anion-Specific Equation Coefficients,
article,
April 26, 2007;
[Washington, D.C.].
(https://digital.library.unt.edu/ark:/67531/metadc335282/:
accessed September 21, 2023),
University of North Texas Libraries, UNT Digital Library, https://digital.library.unt.edu;
crediting UNT College of Arts and Sciences.
