[5,10,15,20-Tetrakis (4-methoxyphenyl)-porphyrinato] zinc dichloromethane disolvate

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Article on 5,10,15,20-tetrakis(4-methoxyphenyl)-porphyrinato] zinc dichloromethane disolvate.

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11 p. : col. ill.

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McGill, Sean; Nesterov, Vladimir N. & Gould, Stephanie L. July 12, 2013.

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Article on 5,10,15,20-tetrakis(4-methoxyphenyl)-porphyrinato] zinc dichloromethane disolvate.

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11 p. : col. ill.

Notes

Abstract: In the title compound, [Zn(C48H36N4O4)]·2CH2Cl2, the ZnII ion lies on an inversion center and is coordinated in an almost ideal square-planar geometry. The asymmetric unit also contains one di­chloro­methane solvent mol­ecule. The unique meth­oxy-substituted benzene rings form dihedral angles of 59.38 (6) and 66.77 (6)° with the mean plane (r.m.s. deviation of fitted atoms = 0.0282 Å) of the atoms in the porphyrin core. The packing is characterized by close contacts between the ZnII ion and two symmetry-related mol­ecules through the O atoms of a meth­oxy­phenyl group [Zn(•••)O = 2.694 (2) Å], forming a two-dimensional network parallel to (100).

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  • Acta Crystallographica Section E, 2013, Chester: International Union of Crystallography

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  • Publication Title: Acta Crystallographica Section E
  • Volume: 69
  • Issue: 8
  • Page Start: m471
  • Peer Reviewed: Yes

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  • July 2, 2013

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  • July 12, 2013

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  • July 12, 2013

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  • Aug. 29, 2014, 2:16 p.m.

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McGill, Sean; Nesterov, Vladimir N. & Gould, Stephanie L. [5,10,15,20-Tetrakis (4-methoxyphenyl)-porphyrinato] zinc dichloromethane disolvate, article, July 12, 2013; [Chester, England]. (digital.library.unt.edu/ark:/67531/metadc333041/: accessed September 24, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT College of Arts and Sciences.