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Article on 5,10,15,20-tetrakis(4-methoxyphenyl)-porphyrinato] zinc dichloromethane disolvate.
Physical Description
11 p. : col. ill.
Notes
Abstract: In the title compound, [Zn(C48H36N4O4)]·2CH2Cl2, the ZnII ion lies on an inversion center and is coordinated in an almost ideal square-planar geometry. The asymmetric unit also contains one diÂchloroÂmethane solvent molÂecule. The unique methÂoxy-substituted benzene rings form dihedral angles of 59.38 (6) and 66.77 (6)° with the mean plane (r.m.s. deviation of fitted atoms = 0.0282 Å) of the atoms in the porphyrin core. The packing is characterized by close contacts between the ZnII ion and two symmetry-related molÂecules through the O atoms of a methÂoxyÂphenyl group [Zn(•••)O = 2.694 (2) Å], forming a two-dimensional network parallel to (100).
Publication Title:
Acta Crystallographica Section E
Volume:
69
Issue:
8
Page Start:
m471
Page End:
sup-10
Peer Reviewed:
Yes
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McGill, Sean; Nesterov, Vladimir N. & Gould, Stephanie L.[5,10,15,20-Tetrakis (4-methoxyphenyl)-porphyrinato] zinc dichloromethane disolvate,
article,
July 24, 2013;
[Chester, England].
(https://digital.library.unt.edu/ark:/67531/metadc333041/:
accessed May 23, 2025),
University of North Texas Libraries, UNT Digital Library, https://digital.library.unt.edu;
crediting UNT College of Arts and Sciences.