Synthesis and Structure of Polynitro- and Polymenthylpolycyclic "Cage" Monomers and Polymers

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The objective of this study was to synthesize and characterize new energetic polycyclic "cage" compounds. As part of a program involved in the synthesis of new polynitropolycyclic compounds, 2,6-dinitro-5-methoxy- 7-carbomethoxypentacyclo[5. 3 .0 . 0* • * . CP • i ° . 0* •8]decane has been synthesized. This is a model system which can be used to study (1) the effect of nitro substitution on the photolability of carbon-carbon double bonds and (2) to develop methods for avoiding Haller-Bauer cleavage in cage /3-keto esters when synthesizing polynitro-substituted cage compounds.

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vi, 133 leaves: ill.

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Jin, Pei-Wen May 1987.

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  • Jin, Pei-Wen

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The objective of this study was to synthesize and characterize new energetic polycyclic "cage" compounds.
As part of a program involved in the synthesis of new polynitropolycyclic compounds, 2,6-dinitro-5-methoxy-
7-carbomethoxypentacyclo[5. 3 .0 . 0* • * . CP • i ° . 0* •8]decane has been synthesized. This is a model system which can be used to study (1) the effect of nitro substitution on the photolability of carbon-carbon double bonds and (2) to develop methods for avoiding Haller-Bauer cleavage in cage /3-keto esters when synthesizing polynitro-substituted cage compounds.

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vi, 133 leaves: ill.

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UNT Theses and Dissertations

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  • May 1987

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  • Aug. 22, 2014, 6 p.m.

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  • March 21, 2016, 10:16 a.m.

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Jin, Pei-Wen. Synthesis and Structure of Polynitro- and Polymenthylpolycyclic "Cage" Monomers and Polymers, dissertation, May 1987; Denton, Texas. (digital.library.unt.edu/ark:/67531/metadc332109/: accessed September 26, 2018), University of North Texas Libraries, Digital Library, digital.library.unt.edu; .