Synthetic, Mechanistic, and Structural Studies of Polynuclear Metal Clusters and Hydrazido-Substituted Tantalum(V) Compounds Page: 3
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characterized octahedral tantalum(V) complex containing a single hydrazido(I) ligand in an all-
nitrogen coordinated environment about the metal center. The fluxional properties of the amido
and hydrazido ligands in these new compounds have been established by VT 1H NMR
spectroscopy (VT = variable temperature). Preliminary data using Ta(NMe2)4[N(TMS)NMe2] as
an ALD (ALD = atomic layer deposition) precursor for the preparation of tantalum nitride and
tantalum oxide thin films are presented.
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Huang, Shih-Huang. Synthetic, Mechanistic, and Structural Studies of Polynuclear Metal Clusters and Hydrazido-Substituted Tantalum(V) Compounds, dissertation, December 2010; Denton, Texas. (https://digital.library.unt.edu/ark:/67531/metadc33166/m1/3/: accessed April 23, 2024), University of North Texas Libraries, UNT Digital Library, https://digital.library.unt.edu; .