Microwave-Assisted Synthesis, Characterization, and Photophysical Properties of New Rhenium(I) Pyrazolyl-Triazine Complexes

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The reaction of the chelating ligand 4-[4,6-bis(3,5-dimethyl-1H-pyrazol-1-yl)-1,3,5-triazin-2-yl]-N,N-diethyl-benzenamine, L, with pentacarbonylchlororhenium by conventional heating method produces the complexes fac-[ReL(CO)3Cl2] and fac-[Re2L(CO)6Cl2] in a period of 48 hours. The use of microwaves as the source of heat and the increase in the equivalents of one of the reactants leads to a more selective reaction and also decreases the reaction time to 1 hour. After proper purification, the photophysical properties of fac-[ReL(CO)3Cl] were analyzed. The solid-state photoluminescence analysis showed an emission band at 628 nm independent of temperature. However, in the solution studies, the emission band shifted from 550 nm in frozen media ... continued below

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Salazar Garza, Gustavo Adolfo May 2010.

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  • Salazar Garza, Gustavo Adolfo

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The reaction of the chelating ligand 4-[4,6-bis(3,5-dimethyl-1H-pyrazol-1-yl)-1,3,5-triazin-2-yl]-N,N-diethyl-benzenamine, L, with pentacarbonylchlororhenium by conventional heating method produces the complexes fac-[ReL(CO)3Cl2] and fac-[Re2L(CO)6Cl2] in a period of 48 hours. The use of microwaves as the source of heat and the increase in the equivalents of one of the reactants leads to a more selective reaction and also decreases the reaction time to 1 hour. After proper purification, the photophysical properties of fac-[ReL(CO)3Cl] were analyzed. The solid-state photoluminescence analysis showed an emission band at 628 nm independent of temperature. However, in the solution studies, the emission band shifted from 550 nm in frozen media to 610 nm when the matrix became fluid. These results confirm that this complex possess a phenomenon known as rigidochromism.

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  • May 2010

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  • Sept. 10, 2010, 1:20 a.m.

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  • Jan. 12, 2011, 1:39 p.m.

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Salazar Garza, Gustavo Adolfo. Microwave-Assisted Synthesis, Characterization, and Photophysical Properties of New Rhenium(I) Pyrazolyl-Triazine Complexes, thesis, May 2010; Denton, Texas. (digital.library.unt.edu/ark:/67531/metadc28473/: accessed December 12, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; .