Polycyclic Aromatic Hydrocarbon Solute Probes. Part 7: Evaluation of Additional Coronene Derivatives as Possible Solvent Polarity Probe Molecules

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Article on polycyclic aromatic hydrocarbon solute probes and the evaluation of additional coronene derivatives as possible solvent polarity probe molecules.

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6 p.

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Acree, William E. (William Eugene); Tucker, Sheryl A. (Sheryl Ann); Zvaigzne, Anita I.; Street, Kenneth W.; Fetzer, John Charles, 1953- & Grützmacher, Hans-Friedrich 1990.

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Article on polycyclic aromatic hydrocarbon solute probes and the evaluation of additional coronene derivatives as possible solvent polarity probe molecules.

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6 p.

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Abstract: Fluorescence emission spectra are reported for dinaphtho[8,1,2abc;2',1',8'klm]coronene, naphtho[8,1,2abc]coronene, naphth[2',1',8',7';4,10,5]anthra[1,9,8abcd]coronene, dibenzo[bc,ef]coronene, benzo[1,2,3bc;4,5,6b'c']dicoronene, anthra[2,3a]coronene, dinaphtho[8,1,2abc;2'1'8'jkl]coronene, and tetrabenzo[de,hi,mn,qr]naphthacene dissolved in n-hexadecane, butyl acetate, dichloromethane, and acetonitrile. Results of these measurements are used to screen PAHs for potential solvent polarity probe behavior. Of the eight PAHs for potential solvent polarity probe behavior. Of the eight PAHs studied, only naphtho[8,1,2abc]coronene, dinaphtho[8,1,2abc;2'1'8'klm]-coronene, and anthra[2,3a]coronene were classified as probe molecules. The fluorescence spectra of the first two PAHs show selective enhancement of the I band emission intensity in polar solvents. For anthra[2,3a]coronene, the measured ratio of emission intensities of band I and II decreased systematically with increasing solvent polarity.

Copyright © 1990 Society for Applied Spectroscopy.

"Part VII."

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  • Applied Spectroscopy, 1990, Frederick: Society for Applied Spectroscopy, pp. 477-482

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  • Publication Title: Applied Spectroscopy
  • Volume: 44
  • Issue: 3
  • Page Start: 477
  • Page End: 482
  • Peer Reviewed: Yes

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  • 1990

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  • April 18, 2014, 5:08 a.m.

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Acree, William E. (William Eugene); Tucker, Sheryl A. (Sheryl Ann); Zvaigzne, Anita I.; Street, Kenneth W.; Fetzer, John Charles, 1953- & Grützmacher, Hans-Friedrich. Polycyclic Aromatic Hydrocarbon Solute Probes. Part 7: Evaluation of Additional Coronene Derivatives as Possible Solvent Polarity Probe Molecules, article, 1990; [Frederick, Maryland]. (digital.library.unt.edu/ark:/67531/metadc283656/: accessed September 25, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT College of Arts and Sciences.