Chemical Equilibria in Binary Solvents

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Dissertation research involves development of Mobile Order Theory thermodynamic models to mathematically describe and predict the solubility, spectral properties, protonation equilibrium constants and two-phase partitioning behavior of solutes dissolved in binary solvent mixtures of analytical importance. Information gained provide a better understanding of solute-solvent and solvent-solvent interactions at the molecular level, which will facilitate the development of better chemical separation methods based upon both gas-liquid and high-performance liquid chromatography, and better analysis methods based upon complexiometric and spectroscopic methods. Dissertation research emphasizes chemical equilibria in systems containing alcohol cosolvents with the understanding that knowledge gained will be transferable to more ... continued below

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x, 337 leaves: ill.

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McHale, Mary E. R. August 1997.

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  • McHale, Mary E. R.

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Description

Dissertation research involves development of Mobile Order Theory thermodynamic models to mathematically describe and predict the solubility, spectral properties, protonation equilibrium constants and two-phase partitioning behavior of solutes dissolved in binary solvent mixtures of analytical importance. Information gained provide a better understanding of solute-solvent and solvent-solvent interactions at the molecular level, which will facilitate the development of better chemical separation methods based upon both gas-liquid and high-performance liquid chromatography, and better analysis methods based upon complexiometric and spectroscopic methods. Dissertation research emphasizes chemical equilibria in systems containing alcohol cosolvents with the understanding that knowledge gained will be transferable to more environmentally friendly aqueous-organic solvent mixtures.

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x, 337 leaves: ill.

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  • August 1997

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  • March 26, 2014, 9:30 a.m.

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  • Aug. 20, 2014, 10:34 a.m.

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McHale, Mary E. R. Chemical Equilibria in Binary Solvents, dissertation, August 1997; Denton, Texas. (digital.library.unt.edu/ark:/67531/metadc278936/: accessed October 22, 2018), University of North Texas Libraries, Digital Library, digital.library.unt.edu; .