Mixed Alkyllithim/Lithium Alkoxide Aggregates with Less Sterically Crowded Alkyl Groups

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Mixed alkyllithium / lithium alkoxide aggregates in the form (RLi)n(ROLi)m were formed by addition of corresponding alcohol compounds at different Li/O ratios. Variable temperature 13C and 6Li NMR spectroscopy were used to verify the formation of the mixed aggregates and to study their behavior in hydrocarbon solution. Spectra for the lithium n-propoxide / n-propyllithium and iso-butyllithium / lithium iso-butoxide systems each indicated at least one mixed aggregate.

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vi, 61 leaves : ill.

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Thornton, Terry L. (Terry Lee), 1962- December 1997.

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  • Thornton, Terry L. (Terry Lee), 1962-

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Mixed alkyllithium / lithium alkoxide aggregates in the form (RLi)n(ROLi)m were formed by addition of corresponding alcohol compounds at different Li/O ratios. Variable temperature 13C and 6Li NMR spectroscopy were used to verify the formation of the mixed aggregates and to study their behavior in hydrocarbon solution. Spectra for the lithium n-propoxide / n-propyllithium and iso-butyllithium / lithium iso-butoxide systems each indicated at least one mixed aggregate.

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vi, 61 leaves : ill.

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  • December 1997

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  • March 24, 2014, 8:07 p.m.

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  • Aug. 14, 2014, 7:41 a.m.

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Thornton, Terry L. (Terry Lee), 1962-. Mixed Alkyllithim/Lithium Alkoxide Aggregates with Less Sterically Crowded Alkyl Groups, thesis, December 1997; Denton, Texas. (digital.library.unt.edu/ark:/67531/metadc278441/: accessed September 21, 2018), University of North Texas Libraries, Digital Library, digital.library.unt.edu; .