3D printing and pressureless sintering of Li2TiO3 for next generation dielectric resonator antennas

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Article demonstrates the fabrication of high-performance lithium titanate (Li₂TiO₃) microwave RF ceramics using direct-write additive manufacturing, achieving densities up to 96.4% and dielectric properties comparable to conventionally manufactured equivalents. The study shows that convergent manufacturing enables low-loss, efficient dielectric resonator antennas with bandwidths of 16–18 GHz and peak gain of 8.42 dBi, highlighting the potential for customizable next-generation ceramic RF materials.

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14 p.

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Summers, Jason M.; Vu, Anh; Maldonado, Jonathan; Bustamantes Evann; Luyen, Hung; Bujanda, Andres et al. March 12, 2025.

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Article demonstrates the fabrication of high-performance lithium titanate (Li₂TiO₃) microwave RF ceramics using direct-write additive manufacturing, achieving densities up to 96.4% and dielectric properties comparable to conventionally manufactured equivalents. The study shows that convergent manufacturing enables low-loss, efficient dielectric resonator antennas with bandwidths of 16–18 GHz and peak gain of 8.42 dBi, highlighting the potential for customizable next-generation ceramic RF materials.

Physical Description

14 p.

Notes

Abstract: Direct-write additively manufactured (AM) high-performance lithium titanate (Li2TiO3) microwave RF ceramic with comparable density, dielectric constant, dielectric loss, and quality factor to traditionally made equivalents is demonstrated. Increasing the surface-to-volume ratio and interfacial free energy in designed electrosteric slurries is shown to be effective for driving pressureless sintering and porosity elimination. A relative density as high as 96.4% was achieved without the application of pressure. Q x F values up to 45,000 GHz, dielectric constants (εᵣ) up to 19, and loss tangents (tanδ) of 1E−3 were achieved at ~ 14 GHz and correlated well with densification. However, compounds such as Li2CO3 and LiCl that formed due to reactions between the dispersing phase and Li2TiO3 and other contaminants could not be completely removed which likely limited the achievable density and dielectric loss. Dielectric resonator antennas fabricated from the printed Li2TiO3 using a convergent manufacturing approach exhibited a bandwidth of 16-18 GHz and gain peaking at 8.42 dBi between 16.25-18.0 GHz. Over this range, the measured total efficiency remained above 90%, highlighting the low-loss nature of the resonator material and structure. The results show the potential of direct-write AM and convergent manufacturing approaches for the development and customization of printed, next-generation, ceramic RF materials and passives.

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  • Scientific Reports, 2025(15), Springer Nature Limited, March 12, 2025, p. 1-14

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  • Publication Title: Scientific Reports
  • Volume: 2025
  • Issue: 15
  • Peer Reviewed: Yes

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  • March 12, 2025

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  • Jan. 13, 2026, 7:23 a.m.

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  • June 29, 2026, 11:33 a.m.

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Summers, Jason M.; Vu, Anh; Maldonado, Jonathan; Bustamantes Evann; Luyen, Hung; Bujanda, Andres et al. 3D printing and pressureless sintering of Li2TiO3 for next generation dielectric resonator antennas, article, March 12, 2025; (https://digital.library.unt.edu/ark:/67531/metadc2565001/: accessed September 10, 2026), University of North Texas Libraries, UNT Digital Library, https://digital.library.unt.edu; crediting UNT College of Engineering.

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