Substrate-Mediated Intermolecular Hybridization in Binary Phthalocyanine Superstructures

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Article on substrate-mediated intermolecular hybridization in binary phthalocyanine superstructures.

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5 p.

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Calzolari, Arrigo; Jin, Wei; Reutt-Robey, Janice E. & Buongiorno Nardelli, Marco 2010.

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Article on substrate-mediated intermolecular hybridization in binary phthalocyanine superstructures.

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5 p.

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Reprinted with permission from the Journal of Physical Chemistry C. Copyright 2010 American Chemical Society.

Abstract: Using a combination of calculations from first principles and scanning tunneling microscopy, we have investigated the interplay between substrate-mediated and intermolecular interactions in the formation of high-density checkerboard binary superstructures from the codeposition of phenyl and perfluorophenyl Zn-phthalocyanines (ZnPc-F₁₆ZnPc) on the Ag(111) surface. The analysis of the electronic structure of the interface shows the essential role played by the substrate in the formation of the molecular layer and opens the way toward the development of tailored surfaces for advanced supramolecular design.

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  • Journal of Physical Chemistry C, 2010, Washington DC: American Chemical Society, pp. 1041-1045

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  • Publication Title: Journal of Physical Chemistry C
  • Volume: 114
  • Issue: 2
  • Page Start: 1041
  • Page End: 1045
  • Peer Reviewed: Yes

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  • 2010

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  • Nov. 8, 2013, 8:29 a.m.

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  • April 1, 2014, 1:33 p.m.

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Calzolari, Arrigo; Jin, Wei; Reutt-Robey, Janice E. & Buongiorno Nardelli, Marco. Substrate-Mediated Intermolecular Hybridization in Binary Phthalocyanine Superstructures, article, 2010; [Washington, DC]. (digital.library.unt.edu/ark:/67531/metadc228285/: accessed December 13, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT College of Arts and Sciences.