Facile and Regioselective C H Bond Activation of Aromatic Substrates by an Fe (II) Complex Involving a Spin-Forbidden Pathway

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Article discussing facile and regioselective C H bond activation of aromatic substrates by an Fe(II) complex involving a spin-forbidden pathway.

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10 p.: ill.

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Kalman, Steven E.; Petit, Alban; Gunnoe, T. Brent; Ess, Daniel H.; Cundari, Thomas R., 1964- & Sabat, Michal Creation Date: Unknown.

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Article discussing facile and regioselective C H bond activation of aromatic substrates by an Fe(II) complex involving a spin-forbidden pathway.

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10 p.: ill.

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Reprinted with permission from Organometallics journal. Copyright 2013 American Chemical Society.

Abstract: The Fe(II) complex Cp*Fe(CO)(NCMe)Ph (Cp* = η⁵-pentamethylcyclopentadienyl) is shown to mediate facile and highly regioselective C H activation of aromatic substrates including benzene, furan, thiophene, thiazole, and 2-methylfuran. Experimental and computational evidence suggest a mechanism for C H activation that involves NCMe dissociation, multiple spin intersystem crossings, C H bond coordination, and C H bond cleavage by a σ-bond metathesis reaction.

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  • Organometallics, 2013, Washington DC: American Chemical Society, pp. 1797-1806

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  • Publication Title: Organometallics
  • Volume: 32
  • Issue: 6
  • Page Start: 1797
  • Page End: 1806
  • Peer Reviewed: Yes

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  • Unknown

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  • February 27, 2013

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  • Sept. 13, 2013, 2:58 p.m.

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  • March 27, 2014, 4:48 p.m.

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Kalman, Steven E.; Petit, Alban; Gunnoe, T. Brent; Ess, Daniel H.; Cundari, Thomas R., 1964- & Sabat, Michal. Facile and Regioselective C H Bond Activation of Aromatic Substrates by an Fe (II) Complex Involving a Spin-Forbidden Pathway, article, Date Unknown; [Washington, DC]. (digital.library.unt.edu/ark:/67531/metadc181681/: accessed April 22, 2018), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT College of Arts and Sciences.