Determination of the Solubilizing Character of 1-(2-Hydroxyethyl)-1-Methylimidazolium Tris(Pentafluoroethyl)Trifluorophosphate Based on the Abraham Solvation Parameter Model
Article discussing the solubilizing character of 1-(2-hydroxyethyl)-1-methylimidazolium tris(pentafluoroethyl)trifluorophosphate based on the Abraham solvation parameter model.
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Article discussing the solubilizing character of 1-(2-hydroxyethyl)-1-methylimidazolium tris(pentafluoroethyl)trifluorophosphate based on the Abraham solvation parameter model.
Abstract: Chromatographic retention factor data were measured for a chemically diverse set of thirty-seven organic solutes on a 1-(2-hydroxyethyl)-3-methylimidazolium tris(pentafluoroethyl)trifluorophosphate ([EtOHMIm]⁺[FAP]⁻) ionic liquid stationary phase at both 323 K and 353 K. The measured retention factors were combined with published gas-to-liquid partition coefficient data for solutes dissolved in ([EtOHMIm]⁺[FAP]⁻) and with published gas-to-water partition coefficient data to yield gas-to-anhydrous ionic liquid and water-to-anhydrous ionic liquid partition coefficients. The three sets of partition coefficients were correlated with the Abraham solvation parameter model. The derived Abraham model correlation describe the experimental gas-to-ionic liquid and water-to-ionic liquid partition coefficient data to within an average standard deviation of 0.12 log units.
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Twu, Pamela; Anderson, Jared L.; Stephens, Timothy W.; Lu, Helen; Satish, Kalpana; Shan, Danyang et al.Determination of the Solubilizing Character of 1-(2-Hydroxyethyl)-1-Methylimidazolium Tris(Pentafluoroethyl)Trifluorophosphate Based on the Abraham Solvation Parameter Model,
article,
2013;
[Hungary].
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accessed March 28, 2024),
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