Determination of the Solubilizing Character of 1-(2-Hydroxyethyl)-1-Methylimidazolium Tris(Pentafluoroethyl)Trifluorophosphate Based on the Abraham Solvation Parameter Model

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Article discussing the solubilizing character of 1-(2-hydroxyethyl)-1-methylimidazolium tris(pentafluoroethyl)trifluorophosphate based on the Abraham solvation parameter model.

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11 p.: ill.

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Twu, Pamela; Anderson, Jared L.; Stephens, Timothy W.; Lu, Helen; Satish, Kalpana; Shan, Danyang et al. 2013.

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Article discussing the solubilizing character of 1-(2-hydroxyethyl)-1-methylimidazolium tris(pentafluoroethyl)trifluorophosphate based on the Abraham solvation parameter model.

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11 p.: ill.

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Copyright © 2013, European Chemical Bulletin. All rights reserved.

Abstract: Chromatographic retention factor data were measured for a chemically diverse set of thirty-seven organic solutes on a 1-(2-hydroxyethyl)-3-methylimidazolium tris(pentafluoroethyl)trifluorophosphate ([EtOHMIm]⁺[FAP]⁻) ionic liquid stationary phase at both 323 K and 353 K. The measured retention factors were combined with published gas-to-liquid partition coefficient data for solutes dissolved in ([EtOHMIm]⁺[FAP]⁻) and with published gas-to-water partition coefficient data to yield gas-to-anhydrous ionic liquid and water-to-anhydrous ionic liquid partition coefficients. The three sets of partition coefficients were correlated with the Abraham solvation parameter model. The derived Abraham model correlation describe the experimental gas-to-ionic liquid and water-to-ionic liquid partition coefficient data to within an average standard deviation of 0.12 log units.

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  • European Chemical Bulletin, 2013, Hungary: Deuton-X Ltd., pp. 954-964

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  • Publication Title: European Chemical Bulletin
  • Volume: 2
  • Issue: 12
  • Page Start: 954
  • Page End: 964
  • Peer Reviewed: Yes

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  • 2013

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  • Sept. 6, 2013, 3:22 p.m.

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  • Aug. 11, 2014, 2:32 p.m.

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Twu, Pamela; Anderson, Jared L.; Stephens, Timothy W.; Lu, Helen; Satish, Kalpana; Shan, Danyang et al. Determination of the Solubilizing Character of 1-(2-Hydroxyethyl)-1-Methylimidazolium Tris(Pentafluoroethyl)Trifluorophosphate Based on the Abraham Solvation Parameter Model, article, 2013; [Hungary]. (digital.library.unt.edu/ark:/67531/metadc180953/: accessed August 22, 2017), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT College of Arts and Sciences.