Correlation of the Solubilizing Abilities of 1-Butyl-1-methyl-pyrrolidinium Tris(pentafluoroethyl)-trifluorophosphate, 1-Butyl-1-methylpyrrolidinium Triflate and 1-Methoxyethyl-1-methylmorpholinium Tris(pentafluoroethyl) trifluorophosphate

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This article discusses the correlation of the solubilizing abilities.

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55 p.

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Twu, Pamela; Anderson, Jared L.; Stephens, Timothy W.; Wilson, Anastasia; Acree, William E. (William Eugene) & Abraham, M. H. (Michael H.) May 2013.

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This article discusses the correlation of the solubilizing abilities.

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55 p.

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This is the pre-published version of this article. The final, definitive version can be found online: http://link.springer.com/article/10.1007%2Fs10953-013-9994-9

Abstract: Chromatographic retention data were measured for a wide range of organic solutes on 1-butyl-1-methylpyrolidinium tris(pentafluoroethyl) trifluorophosphate ([BMPyrr]⁺[FAP]⁻), 1-butyl-1-methylpyrrolidinium triflate, ([BMPyrr]⁺[Trif]⁻), and 1-methoxyethyl-1-methylmorpholinium tris(pentafluoroethyl) trifluorophosphate, ([MeoeMMorp]⁺[FAP]⁻), stationary phases at (323, 353 and 383) K. The measured retention factors were combined with published infinite dilution activity coefficient and gas-to-water partition coefficient data to yield gas-to-anhydrous ionic liquid (IL) and water-to-anhydrous IL partition coefficients. The three sets of partition coefficients were analyzed using the Abraham model. The derived Abraham model correlations describe the observed gas-to-IL (log₁₀ K) and water-to-IL (log₁₀ P) partition coefficient data to within average standard deviations of about 0.11 and 0.15 log₁₀ units, respectively.

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  • Journal of Solution Chemistry, 2013, New York: Springer Science+Business Media

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  • Publication Title: Journal of Solution Chemistry
  • Volume: 42
  • Issue: 4
  • Page Start: 772
  • Page End: 799
  • Peer Reviewed: Yes

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  • May 2013

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  • May 28, 2013, 11 a.m.

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Twu, Pamela; Anderson, Jared L.; Stephens, Timothy W.; Wilson, Anastasia; Acree, William E. (William Eugene) & Abraham, M. H. (Michael H.). Correlation of the Solubilizing Abilities of 1-Butyl-1-methyl-pyrrolidinium Tris(pentafluoroethyl)-trifluorophosphate, 1-Butyl-1-methylpyrrolidinium Triflate and 1-Methoxyethyl-1-methylmorpholinium Tris(pentafluoroethyl) trifluorophosphate, article, May 2013; [New York, New York]. (digital.library.unt.edu/ark:/67531/metadc161694/: accessed November 13, 2018), University of North Texas Libraries, Digital Library, digital.library.unt.edu; crediting UNT College of Arts and Sciences.