Comments on the Competitive Preferential Solvation Theory Metadata

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Title

  • Main Title Comments on the Competitive Preferential Solvation Theory

Creator

  • Author: Acree, William E. (William Eugene)
    Creator Type: Personal
    Creator Info: University of North Texas
  • Author: Zvaigzne, Anita I.
    Creator Type: Personal
    Creator Info: University of North Texas
  • Author: Tucker, Sheryl A. (Sheryl Ann)
    Creator Type: Personal
    Creator Info: University of North Texas

Publisher

  • Name: Royal Society of Chemistry (Great Britain)
    Place of Publication: [Cambridge, England]

Date

  • Creation: 1990

Language

  • English

Description

  • Content Description: Article commenting on the competitive preferential solvation theory.
  • Physical Description: 3 p.

Subject

  • Keyword: preferential solvation theory
  • Keyword: binary solvent mixtures

Source

  • Journal: Journal of the Chemical Society, Faraday Transactions, 1990, Cambridge: Royal Society of Chemistry (Great Britain), pp. 307-309

Citation

  • Publication Title: Journal of the Chemical Society, Faraday Transactions
  • Volume: 86
  • Issue: 2
  • Page Start: 307
  • Page End: 309
  • Peer Reviewed: True

Collection

  • Name: UNT Scholarly Works
    Code: UNTSW

Institution

  • Name: UNT College of Arts and Sciences
    Code: UNTCAS

Rights

  • Rights Access: public

Resource Type

  • Article

Format

  • Text

Identifier

  • DOI: 10.1039/FT9908600307
  • Archival Resource Key: ark:/67531/metadc157300

Degree

  • Academic Department: Chemistry

Note

  • Display Note: Journal of the Chemical Society, Faraday Transactions, 1990, 86:2, pp. 307-309, http://pubs.rsc.org/en/content/articlehtml/1990/ft/ft9908600307
  • Display Note: Abstract: Simple additive relationships for the physico-chemical properties of a solute dissolved in binary solvent mixtures are developed from the competitive preferential solvation model. Additive expressions for solute mole fraction solubility and logarithm of solute solubility are mathematically identical to equations derived previously from the microscopic partition and basic nearly ideal binary solvent models. Calculated values based on the various additive relationships are compared to carbazole solubilities in ten binary solvent mixtures containing dibutyl ether with n-hexane, n-heptane, n-octane, cyclohexane, cyclo-octane, methylcyclohexane, iso-octane, n-hexadecane, squalane and t-butylcyclohexane.