Comments on the Competitive Preferential Solvation Theory Metadata
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- Main Title Comments on the Competitive Preferential Solvation Theory
Author: Acree, William E. (William Eugene)Creator Type: PersonalCreator Info: University of North Texas
Author: Zvaigzne, Anita I.Creator Type: PersonalCreator Info: University of North Texas
Author: Tucker, Sheryl A. (Sheryl Ann)Creator Type: PersonalCreator Info: University of North Texas
Name: Royal Society of Chemistry (Great Britain)Place of Publication: [Cambridge, England]
- Creation: 1990
- Content Description: Article commenting on the competitive preferential solvation theory.
- Physical Description: 3 p.
- Keyword: preferential solvation theory
- Keyword: binary solvent mixtures
- Journal: Journal of the Chemical Society, Faraday Transactions, 1990, Cambridge: Royal Society of Chemistry (Great Britain), pp. 307-309
- Publication Title: Journal of the Chemical Society, Faraday Transactions
- Volume: 86
- Issue: 2
- Page Start: 307
- Page End: 309
- Peer Reviewed: True
Name: UNT Scholarly WorksCode: UNTSW
Name: UNT College of Arts and SciencesCode: UNTCAS
- Rights Access: public
- DOI: 10.1039/FT9908600307
- Archival Resource Key: ark:/67531/metadc157300
- Academic Department: Chemistry
- Display Note: Journal of the Chemical Society, Faraday Transactions, 1990, 86:2, pp. 307-309, http://pubs.rsc.org/en/content/articlehtml/1990/ft/ft9908600307
- Display Note: Abstract: Simple additive relationships for the physico-chemical properties of a solute dissolved in binary solvent mixtures are developed from the competitive preferential solvation model. Additive expressions for solute mole fraction solubility and logarithm of solute solubility are mathematically identical to equations derived previously from the microscopic partition and basic nearly ideal binary solvent models. Calculated values based on the various additive relationships are compared to carbazole solubilities in ten binary solvent mixtures containing dibutyl ether with n-hexane, n-heptane, n-octane, cyclohexane, cyclo-octane, methylcyclohexane, iso-octane, n-hexadecane, squalane and t-butylcyclohexane.